Precipitation polymerization of acrylamide with quaternary ammonium cationic monomer in potassium carbonate solution initiated by plasma

被引:0
|
作者
He, Yangang [1 ]
Li, Gang [1 ]
Yang, Fang [1 ]
Yu, Xueqing [1 ]
Cui, Yingjun [1 ]
Ren, Fengxia [1 ]
机构
[1] School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China
来源
Journal of Applied Polymer Science | 2007年 / 104卷 / 06期
关键词
Precipitation polymerization of 2-(methacryloyloxyethyl) trimethyl ammonium chloride (DMC)-coacrylamide (AM) [poly(AM-DMC)] has been successfully performed in potassium carbonate (K2CO3)-water media by plasma initiation. K2CO3 solution was selected because not only the higher solubility of AM and DMC comparing with that of poly(AM-DMC); but the higher intrinsic viscosity of poly(AM-DMC) could be obtained. A set of experiments was performed using different K2CO3 concentration (from 50 down to 10% (w/w)); thus the precipitation architecture was not obtained below 20% (w/w). And particles size; particles size distribution (7-120 μm); and intrinsic viscosity of poly(AM-DMC) (ranging up to 455 cm3/g) were also summarized in this article. © 2007 Wiley Periodicals; Inc;
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页码:4060 / 4067
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