Formation and properties of hydrogenation catalysts based on palladium bisacetylacetonate and sodium tetrahydroborate

被引：0
|
作者：
Titova, Yu.Yu. [1 ]
Belykh, L.B. [1 ]
Belonogova, L.N. [1 ]
Shmidt, F.K. [1 ]
机构：
[1] Irkutsk State University, Irkutsk, Russia
来源：
Russian Journal of Applied Chemistry | 2009年 / 82卷 / 11期
关键词：
Properties of the Pd(acac)2-nNaBH4 system in catalysis of the reactions of hydrogenation of alkenes; alkynes; and carbonyl and nitro groups were studied. A number of spectral methods (NMR; UV spectroscopy) and X-ray phase analysis were used to examine the main stages of formation of palladium hydrogenation catalysts produced in the interaction of Pd(acac)2 with sodium tetrahydroborate; and reasons for the bimodal nature of the dependence of the catalytic activity on the B/Pd ratio were considered. © 2009 Pleiades Publishing; Ltd;
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页码：1978 / 1985
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