A novel energetic material based on nitro-nno-azoxy: synthesis and characterization

被引：0

作者：

机构：

[1] Li, Hui

[2] Zhao, Feng-Qi

[3] Yu, Qian-Qian

[4] Lai, Wei-Peng

[5] Wang, Bo-Zhou

来源：

Wang, Bo-Zhou (wbz600@163.com) | 1600年 / Institute of Chemical Materials, China Academy of Engineering Physics卷 / 22期

基金：

中国国家自然科学基金;

关键词：

Detonation - Nuclear magnetic resonance - Equations of state - Mass spectrometry;

D O I：

10.11943/j.issn.1006-9941.2014.06.032

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel energetic compound, N, N'-dinitro-N, N'-bis [3- (nitro-NNO-azoxy)furazan-4-yl] methylenediamine, was synthesized using 3-amino-4- (t-Bu-NNO-azoxy)furazan as starting material. And its structure was characterized by nuclear magnetic resonance (1H NMR and 13C NMR), infrared (IR) spectroscopy, elemental analysis and mass spectrometry, and its backbone was also confirmed by the X-ray structure study of the key intermediate. The detonation performance was calculated by VLW equation of state. Results show density is 1.94 g·cm-3, detonation velocity 9502.52 m·s-1, detonation pressure 41.79 GPa and enthalpy of formation 1007.67 kJ·mol-1, indicating it is a competitive energetic materials. ©, 2014, Institute of Chemical Materials, China Academy of Engineering Physics. All right reserved.

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