The influence of metal element types on the formation mechanism and properties of high-entropy ceramic powders and coatings

被引:1
作者
Sun, Wen-wei [1 ]
Hu, Yi [2 ]
Yang, Yong [1 ]
Zhao, Hong-jian [1 ]
Wang, Yan-wei [1 ]
Li, Wei [1 ]
Shao, Yu-xuan [1 ]
Ru, Pei-wen [1 ]
Ma, Yu-duo [1 ,3 ]
Gao, Sheng-yong [4 ]
Li, Ai-min [4 ]
Zhang, Huan-huan [4 ]
机构
[1] Hebei Univ Technol Tianjin, Sch Mat Sci & Engn, Hebei Key Lab New Funct Mat, Hebei Key Lab Superalloy Regenerat Technol,State K, Tianjin 300401, Peoples R China
[2] Hebei Univ Technol Tianjin, Sch Chem Engn & Technol, Tianjin 300401, Peoples R China
[3] Hebei Huabei Diesel Engine Co Ltd, Shijiazhuang 050081, Hebei, Peoples R China
[4] Zhong Hang Shang Da Superalloys Co Ltd, Key Lab Hebei Prov High Temp Alloy Regenerat Techn, Xingtai 054800, Hebei, Peoples R China
基金
中国国家自然科学基金;
关键词
Nanocrystals; High-entropy coating; Mechanical properties; Carbothermal reduction; Solid solution process; HIGH TEMPERATURE CERAMICS; MICROSTRUCTURE; COMPOSITES; CARBIDE;
D O I
10.1016/j.jallcom.2024.177680
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
High entropy carbide ceramics, known for their single-phase formation and tunable properties, have seen limited research on regulating the performance of powders and coatings through elemental changes. This study focused on how different elements affect high entropy phase. Two reaction systems were established using precursors Ta2O5, ZrO2, Nb2O5, TiO2, V2O5, MoO3, and carbon black to explore the impact of two elements on the formation of high-entropy carbide. The (TaZrTiNbV)C and (TaMoTiNbV)C dense coatings were prepared by plasma spraying. The influences of two elements (Zr and Mo) on the phase, microstructure, property, and formation mechanism of the coating were analyzed. The (TaZrTiNbV)C coating showing a hardness of 1762 HV0.1 and a toughness of 3.1 MPa & sdot;m1/2, which were attributed to the presence of finely-grained (TaZrTiNbV)C particles.
引用
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页数:14
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