Spectral evolution of hot hybrid white dwarfs:I. Spectral analysis

Context. Hydrogen-rich white dwarfs (WDs) comprise the majority of the WD population, but are only rarely found at the very hot end of the WD cooling sequence. A small subgroup that exhibits both hydrogen and helium lines in their spectra, the so-called hybrid (or DAO) WDs, represents the majority of hydrogen-rich WDs at effective temperatures Teff approximate to 100 kK. Aims. We aim to understand the spectral evolution of hot hybrid WDs. Although small in number, they represent an evolutionary phase for most (approximate to 75%) WDs. Methods. We conducted a nonlocal thermodynamic equilibrium (NLTE) analysis with fully metal line blanketed model atmospheres for the ultraviolet (UV) and optical spectra of a sample of 19 DA and 13 DAO WDs with Teff > 60 kK. The UV spectra allow us to precisely measure the temperature through model fits to metal lines in different ionization stages. This enables us to place the WDs accurately on the cooling sequence. Results. In contrast to earlier studies that typically relied on temperature measurements made from hydrogen lines alone, all DAOs in our sample are clearly hotter than the DAs. DAOs transform into DAs when they cool to Teff approximate to 75-85 kK, depending on their mass. Along the cooling sequence, we witness a gradual decrease in the abundance of helium and the CNO elements in the DAOs due to gravitational settling. Simultaneously, iron and nickel abundances increase up to the transition region because radiative forces act more efficiently on them. This is followed by a steady decline. We discuss the implications of our results on atomic diffusion theory and on the role of weak radiation-driven winds in hot hydrogen-rich WDs.