π-Bond Dissociation Energies: C-C, C-N, and C-O

被引：1

作者：

Kass, Steven R. ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 89卷 / 20期

基金：

美国国家科学基金会;

关键词：

CIS-TRANS-ISOMERIZATION; MOLECULES; HEATS; W1;

D O I：

10.1021/acs.joc.4c01925

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Single, double, and triple bond dissociation energies are useful quantities, but students and practicing chemists commonly do not know representative values or how they are obtained. In this paper, select pi-bond energies are provided and general methods for their determination are discussed. Relationships between heats of hydrogenation, bond dissociation energies, and pi-bond strengths are also addressed.

引用

页码：15158 / 15163

页数：6

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