π-Bond Dissociation Energies: C-C, C-N, and C-O

被引：1
|
作者：
Kass, Steven R. [1 ]
机构：
[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 89卷 / 20期
基金：
美国国家科学基金会;
关键词：
CIS-TRANS-ISOMERIZATION; MOLECULES; HEATS; W1;
D O I：
10.1021/acs.joc.4c01925
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Single, double, and triple bond dissociation energies are useful quantities, but students and practicing chemists commonly do not know representative values or how they are obtained. In this paper, select pi-bond energies are provided and general methods for their determination are discussed. Relationships between heats of hydrogenation, bond dissociation energies, and pi-bond strengths are also addressed.
引用
收藏
页码：15158 / 15163
页数：6
相关论文
共 50 条
  • [21] Formation and evolution of C-C, C-O, C=O and C-N bonds in chemical reactions of prebiotic interest
    Arias, Alejandro
    Gomez, Sara
    Rojas-Valencia, Natalia
    Nunez-Zarur, Francisco
    Cappelli, Chiara
    Murillo-Lopez, Juliana A.
    Restrepo, Albeiro
    RSC ADVANCES, 2022, 12 (44) : 28804 - 28817
  • [22] Mid-valent organoditantalum chemistry: C-H, C-C, C-O, C-N, and N-O bond activation reactions.
    Messerle, L
    Huang, J
    Lee, TY
    Ting, C
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 211 : 260 - INOR
  • [23] Mechanistic insights into the photocatalytic valorization of lignin models via C-O/C-C cleavage or C-C/C-N coupling
    Zhang, Qingqing
    Gupta, Navneet Kumar
    Rose, Marcus
    Gu, Xiaoli
    Menezes, Prashanth W.
    Chen, Zupeng
    CHEM CATALYSIS, 2023, 3 (02):
  • [24] Practical palladium catalysts for C-N and C-O bond formation
    Muci, AR
    Buchwald, SL
    CROSS-COUPLING REACTIONS: A PRACTICAL GUIDE, 2002, 219 : 131 - 209
  • [25] Universal Bronsted-Evans-Polanyi Relations for C-C, C-O, C-N, N-O, N-N, and O-O Dissociation Reactions
    Wang, Shengguang
    Temel, Burcin
    Shen, Juan
    Jones, Glenn
    Grabow, Lars C.
    Studt, Felix
    Bligaard, Thomas
    Abild-Pedersen, Frank
    Christensen, Claus H.
    Norskov, Jens K.
    CATALYSIS LETTERS, 2011, 141 (03) : 370 - 373
  • [26] New Trends and Future Opportunities in the Enzymatic Formation of C-C, C-N, and C-O bonds
    Sangster, Jack J.
    Marshall, James R.
    Turner, Nicholas J.
    Mangas-Sanchez, Juan
    CHEMBIOCHEM, 2022, 23 (06)
  • [27] REACTIONS INVOLVING THE TRIPLE BOND IN DIMOLYBDENUM AND DITUNGSTEN HEXA-ALKOXIDES AND C-C, C-N, AND C-O TRIPLE BONDS
    CHISHOLM, MH
    HOFFMAN, DM
    HUFFMAN, JC
    CHEMICAL SOCIETY REVIEWS, 1985, 14 (01) : 69 - 91
  • [28] PYROLYSES OF HYDRAZINES AND BENZYLAMINES - C-C AND N-N BOND DISSOCIATION ENERGIES
    KERR, JA
    TROTMANDICKENSO.AF
    SEKHAR, RC
    JOURNAL OF THE CHEMICAL SOCIETY, 1963, : 3217 - &
  • [29] Nickel-Catalyzed, Stereospecific C-C and C-B Cross-Couplings via C-N and C-O Bond Activation
    Xu, Jianyu
    Bercher, Olivia P.
    Talley, Michael R.
    Watson, Mary P.
    ACS CATALYSIS, 2021, 11 (03) : 1604 - 1612
  • [30] Sequential and concerted C-C and C-O bond dissociation in the Coulomb explosion of 2-propanol
    Bittner, Dror M.
    Gope, Krishnendu
    Livshits, Ester
    Baer, Roi
    Strasser, Daniel
    JOURNAL OF CHEMICAL PHYSICS, 2022, 157 (07):
12345