Design and operation analysis on 100-ton scale direct synthesis of DME from biomass synthesis gas

被引:0
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作者
Wang, Tiejun [1 ]
Lv, Yongxing [1 ,3 ]
Wu, Chuangzhi [1 ]
Ma, Longlong [1 ]
Yin, Xiuli [1 ]
Zhang, Xinghua [1 ]
Li, Haibin [1 ]
Cai, Feipeng [2 ]
Sun, Rongfeng [2 ]
Xu, Min [2 ]
Wang, Jianmei [2 ]
机构
[1] Key Laboratory of Renewable Energy and Gas Hydrate, CAS Guangzhou Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China
[2] Energy Research Institute of Shandong Academy of Science, Jinan 250014, China
[3] Graduate University of the Chinese Academy of Sciences, Beijing 100039, China
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Air purification - Biomass - Fuels - Pilot plants;
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摘要
The characteristics of design and operation of a dimethyl-ether (DME) Pilot plant (100ton/y) was introduced. In the Pilot plant, the low ratio of H2/CO synthesis gas was produced by oxygen-rich gasification of corn core. The DME was produced effectively from biomass synthesis gas on the fix-bed one-step DME synthesis process, and then purified successfully by rectifying. The results showed that CO conversion reached 82.00% and 73.55%, and the selectivity of DME are 73.95% and 69.73%. The space time yields are 124.28 kg/(m3·h) and 203.80 kg/(m3·h) when GHSV are 650 h-1 and 1200 h-1, respectively. Deoxidation and tar removals of biomass syngas are critical to the stable operation of DME synthesis system. The H2/CO ratio of purge gas after once-through synthesis is high. It could be reused after removal of CO2, and the yield of DME would be increased greatly.
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页码:1566 / 1570
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