Control of molecular architecture by steric and electronic factors: Dinuclear side-by-side vs. tetranuclear [2 × 2] grid-type silver(i) complexes

被引：31

作者：

Department of Chemistry, University of Otago, P.O. Box 56, Dunedin, New Zealand ^{[1
]}

不详 ^{[2
]}

机构：

[1] Department of Chemistry, University of Otago, Dunedin

[2] Institute of Fundamental Sciences, Chemistry, Massey University, Palmerston North, P.O. Box

来源：

Dalton Trans. | 2006年 / 12卷 / 1491-1494期

关键词：

17;

D O I：

10.1039/b516997f

中图分类号：

学科分类号：

摘要：

The molecular architecture of [2×2] grid-type silver(I) complexes by steric and electronic factors was controlled. Siver(I) complexes of the two closely related linear bis-bidentate pyridazine-based Schiff-based ligands 5 and 6 exhibit very different solid state molecular architectures. The coordination of relatively rigid bis-bidentate ligands to metal ions which prefer a tetrahedral geometry leads to the formation of [2×2] grid complexes. The X-ray crystal structure determination of the product of the 1:1 reaction of silver(I) tetrafluoroborate revealed two distinctly different [2×2] grids.

引用

页码：1491 / 1494

页数：3