Study on the Single and Coupled Combustion Kinetics and Mercury Emission Characteristics of Sewage sludge-coal Slime

被引:0
|
作者
Jia L. [1 ]
Cheng P. [1 ]
Yu Y. [2 ]
Wang Y. [1 ]
Chen S. [1 ]
Wang C. [1 ]
Jin Y. [1 ]
Fan B. [1 ]
Wang J. [3 ]
Zhang J. [4 ]
机构
[1] College of Electrical and Power Engineering, Taiyuan University of Technology, Shanxi Province, Taiyuan
[2] College of Economics and Management, Taiyuan University of Technology, Shanxi Province, Taiyuan
[3] Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology, Shanxi Province, Taiyuan
[4] Taiyuan Boiler Group Co., Ltd, Shanxi Province, Taiyuan
基金
中国国家自然科学基金;
关键词
co-combustion; coal slime; coupled fuel; mercury emission; sewage sludge;
D O I
10.13334/j.0258-8013.pcsee.220645
中图分类号
学科分类号
摘要
Focusing on the single-component and coupled fuel, and considering the complex and changeable co-combustion process, the micro-characteristics of combustion products and the reaction kinetics based on the distributed activation energy model were analyzed to reveal the influence of combustion conditions on the emission process of mercury pollution. The combustion characteristics and evolution process were also clarified, and the mercury emission characteristics under the condition of coupling multiparameters were obtained, aiming at realizing the clean and efficient resource utilization of sewage sludge and coal slime. The results show that the inorganic mercury compounds contained in sewage sludge and coal slime are α-HgS, HgSO4 and HgO with α-type hexagonal structure. The activation energy of sewage sludge increases first and then decreases with the increasing conversion rate; while the activation energy of coal slime is distributed in a "U" shape. The influence of O2 on the combustion and mercury emission process has a critical concentration, which dominates the pyrolysis and heterogeneous combustion of carbonaceous substances and volatiles. The mercury emission process in the coupled fuel co-combustion process is inhibited and promoted at 400~500℃ and 500~600℃ respectively due to the interaction. ©2022 Chin.Soc.for Elec.Eng.
引用
收藏
页码:8618 / 8630
页数:12
相关论文
共 22 条
  • [1] WANG Hui, Songlin LIU, Xiaotong LI, Morphological and structural evolution of bituminous coal slime particles during the process of combustion[J], Fuel, 218, pp. 49-58, (2018)
  • [2] STASTA P,, BORAN J, BEBAR L, Thermal processing of sewage sludge[J], Applied Thermal Engineering, 26, 13, pp. 1420-1426, (2006)
  • [3] Yan LIN, LIAO Yanfen, YU Zhaosheng, The investigation of co-combustion of sewage sludge and oil shale using thermogravimetric analysis[J], Thermochimica Acta, 653, pp. 71-78, (2017)
  • [4] YU Wan, SU Huashan, SUN Qiaomei, Experimental study of the combustion characteristics of municipal sewage sludge at various heating rates and particle size[J], Science Technology and Engineering, 18, 5, pp. 213-217, (2018)
  • [5] MENG Tao, XING Xiaolin, CHEN Chuanheng, Study on co-combustion characteristics and kinetics of mixing fuel of sludge and coal[J], Thermal Power Generation, 50, 5, pp. 87-93, (2021)
  • [6] ZHANG Zili, SUN Guang, DUAN Lunbo, Combustion characteristic and pollutants emission behavior during co-combustion of coal and municipal sewage sludge, Clean Coal Technology, 28, 3, pp. 118-129, (2022)
  • [7] YANG Xucong, LIAO Yanfen, LIN Tao, Numerical Study of 350t/d MSW Incinerator on Sludge Blending Combustion and SNCR Denitration Characteristics [J], Proceedings of the CSEE, 40, 21, pp. 6964-6973, (2020)
  • [8] ZHOU Ke, LIU Haowen, LIU Tianyu, Formation characteristics of particulate matters during the co-combustion of municipal sewage sludge and coal[J], Proceedings of the CSEE, 42, 9, pp. 3286-3295, (2022)
  • [9] GUO Guanghui, CHEN Tongbin, YANG Jun, Regional distribution characteristics and variation of heavy metals in sewage sludge of China[J], Acta Scientiae Circumstantiae, 34, 10, pp. 2455-2461, (2014)
  • [10] YAO Hong, LUO Guangqian, XU Minghou, Study on behaviors of mercury emission during combustion/ gasification processes of coal and sludges[J], Proceedings of the CSEE, 27, 2, pp. 64-68, (2007)