Pyrolysis study of rice husk and rice straw by vacuum ultraviolet photoionization mass spectrometry

被引：0

作者：

Sun, Shao-Bo ^{[1
]}

Weng, Jun-Jie ^{[1
]}

Jia, Liang-Yuan ^{[1
]}

Wang, Yu ^{[1
]}

Qi, Fei ^{[1
]}

Zhou, Zhong-Yue ^{[1
]}

机构：

[1] National Synchrotron Radiation Laboratory, University of Science and Technology of China

来源：

Journal of Chinese Mass Spectrometry Society | 2013年 / 34卷 / 01期

关键词：

Biomass; Photoionization mass spectrometry; Pyrolysis; Rice husk; Rice straw; Synchrotron vacuum ultraviolet(SVUV);

D O I：

10.7538/zpxb.2013.34.01.0001

中图分类号：

学科分类号：

摘要：

The pyrolysis of rice husk and rice straw were studied by tunable synchrotron vacuum ultraviolet photoionization mass spectrometry (SVUV PIMS). Main pyrolysis products of rice husk and rice straw were identified with mass spectra obtained at different photon energies. The work investigated the relation between pyrolysis products and reaction temperature, according to the mass spectra of rice husk and rice straw pyrolysis at different temperatures. Although the TGA spectra showed that the tendency of the TGA spectra of rice husk and rice straw were similar, their mass spectra were different obviously, especially that the m/z 96 and m/z 114, which came from the pyrolysis of hemicellu-lose, changed with temperature differently. The time-dependent profiles of some characteristic products showed that the pyrolysis products from hemicellulose appear rapidly at low temperature, while large proportion of lignin underwent slower thermal decomposition at wider temperature range during the overall pyrolysis process.

引用

页码：1 / 7

页数：6

共 21 条

[1] 1, pp. 25-27, (2006)
[2] 2, pp. 78-82, (2006)
[3] 9, pp. 63-64, (2002)
[4] Bridgwater A.V., Principles and practice of biomass fast pyrolysis processes for liquids, Journal of Analytical and Applied Pyrolysis, 51, 1-2, pp. 3-22, (1999)
[5] 4, pp. 311-316, (2003)
[6] Bahng M.K., Mukarakate C., Robichaud D.J., Et al., Current technologies for analysis of biomass thermochemical processing: A review, Anal Chim Acta, 651, 2, pp. 117-138, (2009)
[7] Z1, pp. 414-425, (2007)
[8] Fei Q., Combustion chemistry probed by synchrotron vuv photoionization mass spectrometry, Proc Combust Inst, 34, (2012)
[9] Pan Y., Zhang L., Guo H., Et al., Photoionisa-tion and photodissociation studies of nonvolatile organic molecules by synchrotron vuv photoionisa-tion mass spectrometry and theoretical calculations, International Reviews in Physical Chemistry, 29, 2, pp. 369-401, (2010)
[10] Fang W.Z., Gong L., Shan X.B., Et al., Thermal desorption/tunable vacuum-ultraviolet time-of-flight photoionization aerosol mass spectrometry for investigating secondary organic aerosols in chamber experiments, Analytical Chemistry, 83, 23, pp. 9024-9032, (2011)

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