Conversion of cyclic vinyl sulfones to transposed vinyl phosphonates

被引：0

作者：

Noshi, Mohammad N. ^{[1
]}

El-awa, Ahmad ^{[1
]}

Torres, Eduardo ^{[1
]}

Fuchs, Philip L. ^{[1
]}

机构：

[1] Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, IN 47907, United States

来源：

Journal of the American Chemical Society | 2007年 / 129卷 / 36期

关键词：

Functionalized cyclic vinyl sulfones were directly converted to the polarity reversed vinyl phosphonates through an efficient one pot procedure. Ozonolysis of these vinyl sulfones and vinyl phosphonates furnish complementary sets of termini-differentiated ester-aldehydes. This strategy has been applied for preparation of segments needed for the synthesis of Aplyronine A. The scope and limitations of this transformation were defined. © 2007 American Chemical Society;

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摘要：

Journal article (JA)

引用

页码：11242 / 11247