Synthesis and magnetic properties of novel complexes of poly(N-2-thiazolylmethacrylamide) with Nd(III), Pr(III), and Sm(III)

被引：0

作者：

Zheng, Ping ^{[1
]}

Sun, Weilin ^{[1
]}

Shen, Zhiquan ^{[1
]}

机构：

[1] Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

来源：

Journal of Applied Polymer Science | 2006年 / 100卷 / 02期

关键词：

N-2-Thiazolylmethacrylamide (NTMA) was polymerized by a radical route to obtain the polymer in good yields. The complexes of PolyNTMA with three rare earth ions Nd(III); Pr(III); and Sm(III) were prepared for the first time. FTIR and 1H NMR were applied to characterize these materials. The magnetic behavior of PolyNTMA-metal complexes was examined as a function of applied magnetic field at 4 K and as a function of temperature (4-300 K) at an applied magnetic field of 30 kOe. It was found that Pr(III) complex exhibits an antiferromagnetic property; while Nd(III) and Sm(III) complexes exhibit a special magnetic property different from the typical magnet. © 2006 Wiley Periodicals; Inc;

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摘要：

Journal article (JA)

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页码：1289 / 1293