Theoretical spectra identification and fluorescent properties of reddish orange Sm-doped BaTiO3 phosphors

被引：0
|
作者：
Zhang, Lei [1 ]
Pan, Hong [1 ]
Liu, Honggang [2 ]
Zhang, Binbin [1 ]
Jin, Long [1 ]
Zhu, Minhao [1 ]
Yang, Weiqing [1 ]
机构：
[1] Key Laboratory of Advanced Technologies of Materials (Ministry of Education), School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu,610031, China
[2] Department of Materials Science, Sichuan University, Chengdu, 610064, China
来源：
Journal of Alloys and Compounds | 2015年 / 643卷
关键词：
Abstract The reddish orange Sm3+-doped tetragonal perovskite BaTiO3 (BTO) phosphors for white LEDs were synthesized by the simple solid state reaction method. These phosphors; which can be effectively excited by the near ultraviolet light 409 nm (6P3/2 (Γ7) → 6H5/2 (Γ7)); produces the emitted reddish orange light peaks locate at about 561 nm; 595 nm and 643 nm originated from the transitions of 4G5/2 (Γ7) → 6H5/2 (Γ7); 4G5/2; (Γ7); →; 6H7/2; and; 6H9/2; Moreover; in order to calculate the fluorescent spectra of these phosphors; the complete 2002 × 2002 energy matrix was successfully constructed by an effective operator Hamiltonian including the free ion and crystal field interactions. Sixteen experimental fluorescent spectra in visible light range for Sm3+ ion at the tetragonal (C4v) Ba2+ site of BTO crystal; firstly; were accurately and quantitatively indentified from a complete diagonalization (of energy matrix) method (CDM) through only five crystal field parameters. The fitting values are very close to the experimental results; evidently proving the capability of CDM to investigate the luminescent phosphors alike in kind for w-LEDs. © 2015 Elsevier B.V. All rights reserved;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
引用
收藏
页码：247 / 252
相关论文
共 50 条
  • [31] Synthesis and fluorescence properties of reddish-orange emitting (Y, Ga)PO4: Sm3+ powder phosphors
    Rambabu, U.
    Han, Sang-Do
    Sailaja, S.
    Reddy, B. Sudhakar
    OPTOELECTRONICS AND ADVANCED MATERIALS-RAPID COMMUNICATIONS, 2012, 6 (9-10): : 777 - 781
  • [32] Luminescence properties of novel orange reddish emitting phosphors KNaCa2(PO4)2:Sm3+
    Yang, Zhiping
    Liu, Pengfei
    Li, Jiaojiao
    Lü, Liang
    Zhao, Yinhong
    Dong, Hongyan
    Hou, Chuncai
    Yang, Z. (yanglpf@163.com), 1600, Chinese Ceramic Society (41): : 782 - 788
  • [33] Synthesis and photoluminescence properties of a novel reddish orange-emitting Sm3+-doped strontium borosilicate phosphor
    Sun, Jianfeng
    Ding, Debao
    Sun, Jiayue
    OPTICAL MATERIALS, 2016, 58 : 188 - 195
  • [34] THEORETICAL INVESTIGATION OF ELECTROMECHANICAL PROPERTIES OF BATIO3 CRYSTAL
    YOKOYAMA, S
    PAK, KN
    KINASE, W
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1974, 36 (03) : 661 - 664
  • [35] Structural and photoluminescence properties of Eu3+-activated BaTiO3 phosphors
    Priya, Ruby
    Sharma, Piyush
    Kumar, Dinesh
    Smriti
    Pandey, O. P.
    JOURNAL OF MOLECULAR STRUCTURE, 2022, 1249
  • [36] Electrical properties of Fe-doped BaTiO3
    Masó, N
    Beltrán, H
    Cordoncillo, E
    Escribano, P
    West, AR
    JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (17) : 1626 - 1633
  • [37] PHOTOFERROELECTRIC PROPERTIES OF CU DOPED BATIO3 CRYSTALS
    OUEDRAOGO, A
    DEHAUT, B
    CHANUSSOT, G
    JOURNAL DE PHYSIQUE LETTRES, 1978, 39 (12): : L179 - L182
  • [38] Electrical properties of BaTiO3 doped with lanthana and niobia
    Mosaad, MM
    El-Ati, MIA
    Olofa, SA
    Ismal, A
    HIGH-PERFORMANCE CERAMICS III, PTS 1 AND 2, 2005, 280-283 : 357 - 359
  • [39] Photoluminescence in disordered Sm-doped PbTiO3: Experimental and theoretical approach
    Lima, R.C.
    Espinosa, J.W.M.
    Gurgel, M.F.C.
    Paris, E.C.
    Leite, E.R.
    Joya, M.R.
    Pizani, P.S.
    Varela, J.A.
    Longo, E.
    Journal of Applied Physics, 2006, 100 (03):
  • [40] Electrical properties of MgO-doped BaTiO3
    Jeong, J
    Han, YH
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (11) : 2264 - 2267
12345