Simultaneous ionic cobalt sensing and toxic Congo red dye removal: a circular economic approach involving silver-enhanced fluorescence

A highly fluorescent quinone-capped silver hydrosol (AgOSA) was obtained using salicylaldehyde and an ionic silver solution. Such metal-enhanced fluorescence was efficiently quenched with Congo red dye (CR), producing CRAgOSA, due to the strong silver-sulfur interaction, replacing the capping of quinone (oxidized salicylaldehyde). The introduction of cobalt ions restored the fluorescence by engaging CR (CoCRAgOSA). Cobalt-induced fluorescence enhancement was 8.3 times higher than that of AgOSA due to the freeing of CR and the release of self-quenching of excess quinone molecules in CoCRAgOSA. The mammoth and selective fluorescence enhancement with ionic cobalt assisted in designing a turn-on ionic cobalt sensor with a limit of detection (LOD) of 9.4 x 10-11 M and a linear detection range (5 x 10-5 to 10-9 M). Moreover, toxic CR dye was eliminated by quinone-capped silver nanoparticles and Co2+ due to chemisorption. Not only the fluorimetric sensing of ionic cobalt but also the colorimetric sensing of Hg2+ was designed due to the simultaneous aggregation of AgNPs and complexation with CR induced by Hg2+ (LOD 1.36 x 10-5 M and linear detection range from 1.00 x 10-4 to 5 x 10-7 M). We applied our sensing method to estimate ionic cobalt and mercury in natural samples. The experiment was a unique case of circular economy, where a toxic dye was used for making a nanosensor. Fluorometric and colorimetric sensing of metal ions with environmental remediation.