Synthesis and characterization of thermal properties of poly(p-cumylphenyl methacrylate-co-methoxyethyl methacrylate) copolymers

被引:1
|
作者
Parthiban, E. [1 ]
Sudarsan, S. [2 ]
Charles, A. [3 ]
Mohan, S. [4 ]
Kumar, A. [5 ]
Kistan, A. [6 ]
机构
[1] C Abdul Hakeem Coll Engn & Technol, Dept Chem, Melvisharam 632509, Tamil Nadu, India
[2] South Ural State Univ, Chelyabinsk 454080, Russia
[3] Kings Engn Coll, Dept Chem, Chennai 602117, Tamil Nadu, India
[4] Rajalakshmi Engn Coll, Dept Chem, Chennai 602105, Tamil Nadu, India
[5] Saveetha Engn Coll, Dept Chem Engn, Chennai 602105, Tamil Nadu, India
[6] Panimalar Engn Coll, Dept Chem, Chennai 600123, Tamil Nadu, India
关键词
p-cumylphenyl methacrylate; Methoxyethyl methacrylate; Thermal stability; Free radical polymerization; Copolymers; GLYCIDYL METHACRYLATE; PHASE-SEPARATION; POLYMERIZATION;
D O I
10.1016/j.molstruc.2024.140890
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The poly(p-cumylphenyl methacrylate-co-methoxyethyl methacrylate) copolymers has been fabricated in a simple way. The p-cumylphenyl methacrylate and methoxy methacrylate were polymerized by free radical mechanism using benzoyl peroxide as an initiator. The synthesized copolymers were confirmed by Fourier transform infrared spectroscopy (FTIR), proton nuclear magnetic resonance (1H NMR) and carbon nuclear magnetic resonance (13C NMR) spectral techniques. The heat durability of copolymers has been investigated by Thermogravimetric analysis (TGA), derivative thermogravimetry, and differential thermal analysis (DTA). The glass transition temperature (Tg) of copolymer was carried out using differential scanning calorimetry (DSC). The scanning electron microscopy (SEM) was utilized to observe the surface texture and morphology roughness of copolymers. The obtained copolymers have possess an excellent coating property, anti-corrosive property, and optical property. Hence, these can be utilize in different way like solar, sensors, polymer conductivity, battery electrolytes, nanotechnology, viscosity, and biomedical.
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页数:7
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