Synthesis and structural analysis of hydronopyl formic acid and its esters

被引：0

作者：

机构：

[1] College of Forestry, Jiangxi Agricultural University

[2] College of Chemistry, Jiangxi Normal University

[3] Library, Jiangxi Agricultural University

来源：

Wang, Z.-D. (zongdewang@163.com) | 1600年 / Editorial Board of Chemistry and Industry of Forest Products, No. 16 Suojin Wucun, Nanjing, 210042, China卷 / 33期

关键词：

Esterification; Grignard reaction; Hydronopyl chloride; Hydronopyl formic acid; Structure analysis;

D O I：

10.3969/j.issn.0253-2417.2013.04.011

中图分类号：

O62 [有机化学]; TQ [化学工业];

学科分类号：

070303 ; 0817 ; 081704 ;

摘要：

Hydronopyl magnesium chloride was prepared through the Grignard reaction of hydronopyl chloride and magnesium in solvent of ether. Hydronopylformic acid was obtained from the hydrolyze reaction of diluted hydrochloric acid with the injection of CO2. Then six kinds of hydronopylformic acid esters were synthesized from the reaction of hydronopyl formic acid with methanol, ethanol, propanol, butanol, pentanol and hexanol with oxalic acid as catalyst respectively. The yields of the products (GC contents were over 98%) were more than 85%. The structures of the products were characterized and analyzed by IR, 1H NMR, 13C NMR and MS methods.

引用

页码：57 / 61

页数：4

共 10 条

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