Molybdenum(VI) dichloride

被引：0
作者：
Department of Chemistry, Indian Institute of Technology Madras, Chennai 600 036, India [1 ]
机构：
[1] Department of Chemistry, Indian Institute of Technology Madras
来源：
Synthesis | 2009年 / 2卷 / 306-310期
关键词：
β-hydroxycarbonyl compounds; Bromination; Molybdenum; N-bromosuccinimide; Oxidation;
D O I：
10.1055/s-0028-1083273
中图分类号：
学科分类号：
摘要：
A novel and efficient method for the one-pot transformation of β-hydroxycarbonyl compounds to a-brominated 1,3-dicarbonyl compounds is achieved with MoO2Cl2 in the presence of N-bromosuccinimide. All the reactions were carried out under mild conditions and provide good yields of the products. No bromination occurs at benzylic and allylic positions. © Georg Thieme Verlag Stuttgart · New York.
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页码：306 / 310
页数：4
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