Development of highly thermal-stable blue emitting Y4Al2O9:Bi3+phosphors for w-LEDs, fingerprint and data security applications

被引:11
作者
Arunakumar, R. [1 ]
Krushna, B. R. Radha [2 ]
Ramakrishna, G. [1 ]
Mamatha, G. R. [2 ]
Sharma, S. C. [3 ]
Kumar, Satish [4 ]
Suvarna, P. [5 ]
Mohapatra, Liza [6 ]
George, Augustine [7 ]
Sudarmani, R. [8 ]
Nagabhushana, H. [2 ]
机构
[1] Tumkur Univ, Univ Coll Sci, Dept Phys, Tumkur 572103, India
[2] Tumkur Univ, Prof CNR Rao Ctr Adv Mat, Tumakuru 572103, India
[3] Jain Univ, Law & Forens Mat, Bangalore 562112, India
[4] Mahatma Gandhi Med Coll & Res Inst, Dept Forens Med & Toxicol, Pondicherry 607402, India
[5] Meenakshi Med Coll Hosp & Res Inst, Meenakshi Acad Higher Educ & Res, Dept Obstet & Gynaecol, Chennai 600095, India
[6] SOA Univ, IMS & SUM Hosp, Dept Dermatol, Bhubaneswar 751003, Odissa, India
[7] Kristu Jayanti Coll Autonomous, Dept Comp Sci, Bengaluru 560077, India
[8] Avinashilingam Inst Home Sci & Higher Educ Women, Sch Engn, Dept Elect & Commun Engn, Coimbatore 641108, India
来源
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS | 2025年 / 312卷
关键词
Phosphor; Photoluminescence; w-LEDs; Latent fingerprints; Anti-counterfeiting; LUMINESCENCE PROPERTIES; PHOSPHOR; PHOTOLUMINESCENCE; BI3+; MODULATION; EXCITATION;
D O I
10.1016/j.mseb.2024.117833
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A new blue-emitting Y4Al2O9:Bi3+ (YAO:Bi3+) phosphor is synthesized using the solution combustion method A new blue-emitting Y4Al2O9:Bi3+ (YAO:Bi3+) phosphor is synthesized using the solution combustion method with mushroom extract as a binder. Its structural properties, concentration effects, temperature-dependent with mushroom extract as a binder. Its structural properties, concentration effects, temperature-dependent luminescence, and performance in LED devices are thoroughly investigated. Upon excitation at 367 nm, a luminescence, and performance in LED devices are thoroughly investigated. Upon excitation at 367 nm, a strong blue light emission at 423 nm is observed, attributed to the 3P1 -> 1S0 transition of Bi3+. The quantum strong blue light emission at 423 nm is observed, attributed to the 3P1 -> 1S0 transition of Bi3+. The quantum efficiency reached approximately 63.5 %. The CIE diagram shows that the emission colour falls within the efficiency reached approximately 63.5 %. The CIE diagram shows that the emission colour falls within the intense blue region, achieving a colour purity (CP) of 94 %. YAO:Bi3+ exhibits strong absorption in the nearintense blue region, achieving a colour purity (CP) of 94 %. YAO:Bi3+ exhibits strong absorption in the nearultraviolet range (330-400 nm), making it suitable for LEDs powered by near-ultraviolet chips. A thermal ultraviolet range (330-400 nm), making it suitable for LEDs powered by near-ultraviolet chips. A thermal quenching experiment revealed an activation energy (Ea) of 0.323 eV, indicating that this YAO:Bi3+ phosphor quenching experiment revealed an activation energy (Ea) of 0.323 eV, indicating that this YAO:Bi3+ phosphor possesses good thermal stability. This study showcases the use of YAO:Bi3+ phosphor in encapsulated LED depossesses good thermal stability. This study showcases the use of YAO:Bi3+ phosphor in encapsulated LED devices. The device's Commission Internationale de l'E<acute accent>clairage (CIE) coordinates are (0.325, 0.310), with a high vices. The device's Commission Internationale de l'E<acute accent>clairage (CIE) coordinates are (0.325, 0.310), with a high colour rendering index (CRI) of 94.70 and a low correlated colour temperature (CCT) of 5915 K at a current of colour rendering index (CRI) of 94.70 and a low correlated colour temperature (CCT) of 5915 K at a current of 120 mA. These properties indicate that this phosphor is suitable for developing white LED devices powered by 120 mA. These properties indicate that this phosphor is suitable for developing white LED devices powered by near-ultraviolet chips. The optimized YAO:Bi3+ phosphor is employed to enhance the detection of Level I-III near-ultraviolet chips. The optimized YAO:Bi3+ phosphor is employed to enhance the detection of Level I-III fingerprint (FP) details with high resolution and contrast, showing effective visualization of latent fingerprints fingerprint (FP) details with high resolution and contrast, showing effective visualization of latent fingerprints (LFPs) on various substrates. Furthermore, it is used as a model for developing fluorescent ink, which is applied (LFPs) on various substrates. Furthermore, it is used as a model for developing fluorescent ink, which is applied to different media. The results suggest that YAO:Bi3+ phosphor has significant potential for applications in wto different media. The results suggest that YAO:Bi3+ phosphor has significant potential for applications in wLEDs, advanced forensics, and anti-counterfeiting ink technologies. LEDs, advanced forensics, and anti-counterfeiting ink technologies.
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页数:24
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