Magnetic properties of CaRu1-xFexO3

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作者
Mizusaki, S. [1 ]
Taniguchi, T. [1 ]
Okada, N. [1 ]
Nagata, Y. [1 ]
Hiraoka, N. [2 ]
Nagao, T. [3 ]
Itou, M. [4 ]
Sakurai, Y. [4 ]
Ozawa, T.C. [5 ]
Noro, Y. [6 ]
机构
[1] College of Science and Engineering, Aoyama Gakuin University, Sagamihara, Kanagawa 157-8572, Japan
[2] National Synchrotron Radiation Research Center, Hsinchu Science Park, Taiwan 101 Hsin-Ann Road, Hsinchu 30076, Taiwan
[3] Graduate School of Material Science, University of Hyogo, Kamigori, Ako-gun, Hyogo 678-1297, Japan
[4] Japan Synchrotron Radiation Research Institute (JASRI/Spring-8), Sayo, Mikazuki, Hyogo, 679-5198, Japan
[5] International Center for Young Scientists, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan
[6] Kawazoe Frontier Technologies, Co. Ltd., Sakae, Yokohama, Kanagawa 931-113, Japan
来源
Journal of Applied Physics | 2006年 / 99卷 / 08期
关键词
The occurrence of ferromagnetism was studied in the Ca Ru1-x Fex O3 system by means of magnetic Compton scattering; Mössbauer effect; and magnetization measurements using polycrystalline specimens. Ferromagnetism is induced for extremely small Fe doping (x≥0.02) to paramagnetic CaRu O3; and the TC increases as the Fe content increases. The temperature dependence of reciprocal magnetic susceptibility shows a characteristic of ferrimagnetism. A sextet with an isomer shift of the Fe3+ ion and the hyperfine field of about 450 kOe were observed in the Mössbauer effect measurement below TC; suggesting the existence of magnetic order. The magnetic Compton scattering experiment revealed the occurrence of a large magnetic moment on Ru and an antiferromagnetic coupling between Fe and Ru spin moments. A possible model for the occurrence of ferrimagnetism has been proposed. © 2006 American Institute of Physics;
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