Voltammetric determination of lead (II) ions at carbon paste electrode modified with banana tissue

被引:0
作者
Institute of Chemistry, University of the Philippines, Los Baños, Philippines [1 ]
机构
[1] Institute of Chemistry, University of the Philippines, Los Baños
来源
J. Appl. Sci. | 2007年 / 9卷 / 1286-1292期
关键词
Banana tissue; Carbon paste electrode; Lead; Modifier;
D O I
10.3923/jas.2007.1286.1292
中图分类号
学科分类号
摘要
Banana tissue contains materials with functional groups which have the ability to form complexes with metal ions. With this property, banana tissue was used as modifier of carbon paste electrode for voltammetric determination of lead ions in aqueous samples. The use of 0.01 M HCl as supporting electrolyte and 20% (w/w) modifier gave an optimum current response for lead (II) solution. Accumulation time of 6 min, accumulating solution of pH 5, deposition time of 300 sec and deposition potential of-1500 mV were found to give the best results in the analysis of lead (II). Multiple stripping of the used electrode successfully removed lead ions for the regeneration of the electrode. The banana modified carbon paste electrode exhibited a sensitivity of 2.81 μA/ppm and a limit of detection (LOD) of 0.10 mg L-1. © 2007 Asian Network for Scientific Information.
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页码:1286 / 1292
页数:6
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共 22 条
[1]  
Agraz R., Sevilla M.T., Hernadez L., Chemically modified electrode for the simultaneous determination of trace metals and speciation analysis, Anal. Chim. Acta, 273, pp. 205-212, (1993)
[2]  
Agusa T., Kunito T., Ramu K., Chamnan C., Trang P.T.K., Mirth T.B., Subramanian A., Iwata H., Viet P.H., Tana T.S., Tanabe S., Lead contamination and its human health effects in India, Vietnam and Cambodia, Biomed. Res. Trace Elements, 17, pp. 413-416, (2006)
[3]  
Bartlett P.N., Denuarret G., Souza M.F.B., A study of the preconcentration and stripping voltammetry of Pb(II) at carbon electrodes, Analyst, 125, pp. 1135-1138, (2000)
[4]  
Brainina K.H.Z., Neyman E., Electrochemical stripping methods, pp. 71-77, (1993)
[5]  
Chen Y., Tan T.C., Modeling and experimental study of the transient behavior of plant tissue sensors in sensing dopamine, Chem. Eng. Sci, 51, pp. 1027-1042, (1996)
[6]  
Elvina Jr. R.O., Mojica E.R.E., Orange peel essential oil as component of a metal sensor for lead (II) ions in aqueous samples, J. Applied Sci. Environ. Manage, 9, pp. 23-27, (2005)
[7]  
Fry A.J., Solvents and Supporting Electrolytes, Laboratory Techniques in Electroanalytical Chemistry, pp. 469-486, (1996)
[8]  
Gardea-Torresdey J., Darnall D., Wang J., Bioaccumulation and measurement of copper at an alga-modified carbon paste electrode, Anal. Chem, 60, pp. 72-76, (1988)
[9]  
Gooding J.J., Hibbert D.B., Yang W., Electrochemical metal ions sensors, exploiting amino acids and peptides as recognitions elements, Sensors, 1, pp. 75-90, (2001)
[10]  
Gosser Jr. D.K., Cyclic Voltammetry: Simulation and Analysis of Reaction Mechanisms, (1993)