Effect of Iron Oxide on Sulfide Capacities of CaO-SiO2-FeO and CaO-Al2O3-FeO Ternary Systems

被引:0
作者
Hasegawa, Masakatsu [1 ]
Saito, Keijiro [2 ]
Awaya, Kosuke [3 ]
Mitsuyama, Domu [4 ]
机构
[1] Kyoto Univ, Dept Energy Sci & Technol, Yoshida Hon Machi,Sakyo Ku, Kyoto 6068501, Japan
[2] Univ Tokyo, Kyoto Univ, Dept Mat Engn, Grad Sch Engn, 7-3-1 Hongo,Bunkyo Ku, Kyoto 1138656, Japan
[3] Kyoto Univ Now, Nippon Steel Corp, 2-6-1 Marunouchi,Chiyoda Ku, Tokyo 1008071, Japan
[4] Kyoto Univ Now, Tokyo Elect Power Co Holdings Inc, I-1-3 Uchisaiwai Cho,Chiyoda Ku, Tokyo 1008560, Japan
关键词
sulfide capacity; activity; iron oxide; sulfur distribution ratio; re-sulfurization; LIQUID-IRON; SULFUR; SLAGS; EQUILIBRIA; SILICATE; TEMPERATURE; MELTS; FEO;
D O I
10.2355/isijinternational.ISIJINT-2024-267
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Towards steelmaking processes which are compatible with the sustainable society, re-sulfurization reaction in hot metal pre-treatments needs to be suppressed as much as possible. To evaluate the effects of iron oxide on the sulfur distribution ratio between FeO-containing slag and hot metal, sulfide capacities and FeO activities were measured in CaO-SiO2-FeO and CaO-Al2O3-FeO ternary liquid slags. Although the FeO activity and oxygen potential increased, the addition of FeO raised sulfide capacity drastically and resulted in an increase in the calculated value for distribution ratio of sulfur.
引用
收藏
页码:2144 / 2148
页数:5
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