Self-assembly of tetra nuclear lanthanide (Pr, Nd) hydroxo clusters with functionalized β-diketone: Experimental and theoretical studies

被引：0

作者：

Jami, Ananda Kumar ^{[1
]}

Kishore, Pilli V. V. N. ^{[2
]}

Srinivasadesikan, Venkatesan ^{[2
]}

Tripuramallu, Bharat Kumar ^{[2
]}

Rao, Maddina Sreenivasa ^{[3
]}

机构：

[1] Godavari Global Univ, Dept Chem, Rajamahendravaram 533296, Andhra Pradesh, India

[2] Vignans Fdn Sci Technol & Res, Sch Appl Sci & Humanities, Dept Chem, Guntur 522213, India

[3] Godavari Global Univ, Dept Mech Engn, Rajamahendravaram 533296, Andhra Pradesh, India

来源：

POLYHEDRON | 2025年 / 266卷

关键词：

Functionalization; beta-Diketones; Lanthanide hydroxo clusters; Structural topology; SINGLE-MOLECULE MAGNET; STRUCTURAL-CHARACTERIZATION; TRANS-A(2)B(2) PORPHYRINS; CRYSTAL-STRUCTURE; AMINO-ACIDS; COMPLEXES; COORDINATION; TETRANUCLEAR; LIGAND; REACTIVITY;

D O I：

10.1016/j.poly.2024.117306

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of LnCl3 & sdot;6H2O (Ln = Pr, Nd) with functionalized beta-Diketone {ortho-hydroxydibenzoylmethane (HODBM)} in 1:2 ratio in methanol and in presence of triethylamine (excess) as base yielded two tetra nuclear lanthanide hydroxo clusters of composition [Ln4(O-DBM)4(HO-DBM)4(mu 3-OH)2][Et3NH]2.3CH2Cl2, (Ln = Pr (1), Nd (2)). The clusters 1 and 2 has been structurally characterized by single crystal X-ray diffraction. A onedimensional supramolecular chain is observed in the solid state structure (2), where dichloromethane solvent molecules are linked to the phenyl rings of adjacent diketone linkers through C-H & ctdot;pi and Cl & ctdot;pi interactions. Theoretical studies support the stability of structure (2), with calculated geometric parameters aligning with experimental findings.

引用

页数：7

共 2 条

[1] 2-hydroxybenzophenone-controlled self-assembly of enneanuclear lanthanide(III) hydroxo coordination clusters with an "hourglass"-like topology
Mylonas-Margaritis, Ioannis
Kitos, Alexandros A.
Panteli, Chrysanthi C.
Skordi, Katerina
Tasiopoulos, Anastasios J.
Bekiari, Vlasoula
Escuer, Albert
Perlepes, Spyros P.
INORGANIC CHEMISTRY COMMUNICATIONS, 2017, 83 : 118 - 122
[2] Self-assembly of tetra-nuclear lanthanide clusters via atmospheric CO2 fixation: interesting solvent-induced structures and magnetic relaxation conversions
Wang, Wen-Min
Wu, Zhi-Lei
Zhang, Ya-Xin
Wei, Hai-Ying
Gao, Hong-Ling
Cui, Jian-Zhong
INORGANIC CHEMISTRY FRONTIERS, 2018, 5 (09): : 2346 - 2354

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