Tribological properties of plasma nitriding GCr15 steel under lubrication with borate containing nitrogen additive

被引:0
作者
Wang, Song [1 ]
Yue, Wen [1 ]
Wang, Chengbiao [1 ]
Gao, Xiaocheng [1 ]
Bu, Hongli [1 ]
Liu, Jiajun [2 ]
机构
[1] School of Engineering and Technology, China University of Geosciences(Beijing)
[2] Department of Mechanical Engineering, Tsinghua University
来源
Jixie Gongcheng Xuebao/Journal of Mechanical Engineering | 2012年 / 48卷 / 19期
关键词
Borate containing nitrogen additive; Plasma nitriding; Tribological property;
D O I
10.3901/JME.2012.19.128
中图分类号
学科分类号
摘要
An approach combining the plasma nitriding with lubrication additive is proposed to improve the durability of the antifriction bearing. The nitrided layer on GCr15 steel is prepared in a plasma nitriding furnace. Its surface morphologies, phase structure, and hardness are analyzed by means of scanning electron microscope (SEM), X-ray diffractometer (XRD) and microhardness tester. Its friction and wear behaviors are examined on a four-ball friction and wear tester under lubrication with borate containing nitrogen additive, compared with that of plain GCr15 steel. The composition and chemical binding state of tribofilm formed on the wear steel surface is analyzed by X-ray photoelectron spectroscope (XPS). The results show that an unexpected excellent synergistic effect occur between the nitrided surface and additive, the nitrided steel exhibits lower friction coefficient and better anti-wear properties compared with untreated steel, especially when 1.25% additive is used, the friction coefficient and wear scar diameter reduce by 34% and 45% separately. The main mechanism of this effect is attributed to that the borate containing nitrogen additive can produce a tribofilm containing higher content of BN on the nitrided surface, which is not found on the plain steel surface. © 2012 Journal of Mechanical Engineering.
引用
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页码:128 / 133
页数:5
相关论文
共 20 条
[1]  
Qin H., Shen X., How to extend the using life of the rolling bearing, China's Foreign Trade, 14, (2010)
[2]  
Ouyang P., Chen G., Li H., Researching trend of traditonal antiwear agents in lubricating oils, Lubrication Engineering, 31, 6, pp. 165-168, (2006)
[3]  
Li X., Yang Y., The progress of research on boric compounds as extreme-pressure antiwear and friction-reducing lubricant additive, Lubrication Engineering, 31, 9, pp. 197-205, (2006)
[4]  
Pawlak Z., Kaldonski T., Urbaniak W., A hexagonal boron nitride-based model of porous bearings with reduced friction and increased load, Journal of Mechanical Engineering, 24, 12, pp. 1247-1253, (2010)
[5]  
Shen G., Zhen Z., Wan Y., Hydrolytic stability and triboligical properties of organic borate esters as lubricant additives, Journal of Tsinghua University, 39, 10, pp. 97-100, (1999)
[6]  
Huang W., Liao L., Deng G., An investigation of the tribological properties of aqueous borate containing nitrogen, Lubrication Engineering, 26, 5, pp. 29-30, (2001)
[7]  
Liu G., Hu Y., Sun X., Et al., The study on performance of the borate ester containing nitrogen as lubricant additive, Lubrication Engineering, 29, 2, pp. 114-116, (2004)
[8]  
Huang W., Chen B., Dong J., Study on the tribological properties of water-soluble borate, Chinese Journal of Mechanical Engineering, 37, 5, pp. 18-22, (2001)
[9]  
Yao J., Antiwear function and mechanism of a nitrogen-containing borate ester as lubricant additive, Lubricating Oil, 21, 1, pp. 41-44, (2006)
[10]  
Chai D., Han X., Wang X., Et al., Synthesis and tribological properties of nitrogencontaining heterocyclic borate, Lubrication Engineering, 34, 12, pp. 18-22, (2009)