Selective reduction of carbonyl and epoxy compounds using aluminum, boron and other metal reagents. Comparison of reducing characteristics between the Meerwein-Ponndorf-Verley type reduction and metal complex hydrides reduction: A review

被引:0
作者
Department of Chemistry, Yeungnam University, Gyongsan 712-749, Korea, Republic of [1 ]
机构
[1] Department of Chemistry, Yeungnam University
来源
Bull. Korean Chem. Soc. | 2007年 / 12卷 / 2162-2190期
关键词
Aluminum and boron reagents; Carbonyl and epoxy compounds; Metal complex hydrides; MPV reactions; Reduction;
D O I
10.5012/bkcs.2007.28.12.2162
中图分类号
学科分类号
摘要
The newly-developed Meerwein-Ponndorf-Verley (MVP) type reagents using aluminum, boron and other metals for reduction of organic functional groups such as carbonyl and epoxy compounds have been surveyed. highlighted and reviewed in this account are the appearance of new MPV type reagents and their application to the selective reduction of organic functions. Finally, this account emphasizes the distinct contrast in the reducing characteristics existed between metal hydride reagents and MPV reagents, and compares their usefulness in organic synthesis.
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页码:2162 / 2190
页数:28
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