Shear-induced transitions and instabilities in surfactant wormlike micelles

被引:0
作者
Lerouge S. [1 ]
Berret J.-F. [1 ]
机构
[1] Laboratoire Matière et Systèmes Complexes (MSC), UMR 7057 CNRS-Université Paris-Diderot, F-75205 Paris Cedex 13
关键词
Instabilities under shear; Lyotropic mesophases; Shear-banding; Shear-thickening; Surfactant; Viscoelasticity; Wormlike micelles;
D O I
10.1007/12-2009-13
中图分类号
学科分类号
摘要
In this review, we report recent developments on the shear-induced transitions and instabilities found in surfactant wormlike micelles. The survey focuses on the nonlinear shear rheology and covers a broad range of surfactant concentrations, from the dilute to the liquid-crystalline states and including the semidilute and concentrated regimes. Based on a systematic analysis of many surfactant systems, the present approach aims to identify the essential features of the transitions. It is suggested that these features define classes of behaviors. The review describes three types of transitions and/or instabilities: the shear-thickening found in the dilute regime, the shear-banding which is linked in some systems to the isotropic-to-nematic transition, and the flow-aligning and tumbling instabilities characteristic of nematic structures. In these three classes of behaviors, the shear-induced transitions are the result of a coupling between the internal structure of the fluid and the flow, resulting in a new mesoscopic organization under shear. This survey finally highlights the potential use of wormlike micelles as model systems for complex fluids and for applications. © 2010 Springer-Verlag Berlin Heidelberg.
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页码:1 / 71
页数:70
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  • [1] Debye P., Anacker E., Micelle shape from dissymetry measurements, J Phys Chem, 55, pp. 644-655, (1951)
  • [2] Nash T., The interaction of some naphtalene derivatives with a cationic soap below the critical micelle concentration, J Colloid Sci, 13, pp. 134-139, (1958)
  • [3] Gravsholt S., Viscoelasticity in highly dilute aqueous solutions of pure cationic detergents, J Colloid Interface Sci, 57, pp. 575-577, (1976)
  • [4] Porte G., Appell J., Poggi Y., Experimental investigations on the flexibility of elongated cetylpyridinium bromide micelles, J Phys Chem, 84, pp. 3105-3110, (1980)
  • [5] Porte G., Appell J., Growth and size distributions of cetylpyridinium bromide micelles in high ionic strength aqueous solutions, J Phys Chem, 85, pp. 2511-2519, (1981)
  • [6] Ikeda S., Sphere-rod transition of surfactant micelles and size distribution of rodlike micelles, J Phys Chem, 88, pp. 2144-2149, (1984)
  • [7] Candau S.J., Hirsch E., Zana R., Light scattering investigations of the behavior of semidilute aqueous micellar solutions of cetyltrimethylammonium bromide: Analogy with semidilute polymer solutions, Journal of Colloid and Interface Science, 105, 2, pp. 521-528, (1985)
  • [8] Imae T., Kamiya R., Ikeda S., Electron microscopic observation of rod-like micelles of dimethyloleylamine oxide regenerated from its aqueous solutions, Journal of Colloid and Interface Science, 99, 1, pp. 300-301, (1984)
  • [9] Imae T., Kamiya R., Ikeda S., Formation of spherical and rod-like micelles of cetyltrimethylammonium bromide in aqueous NaBr solutions, Journal of Colloid and Interface Science, 108, 1, pp. 215-225, (1985)
  • [10] Imae T., Ikeda S., Sphere-rod transition in micelles of tetradecyltrimethylammonium halides in aqueous sodium halide solutions and flexibility and entanglement of long rodlike micelles, J Phys Chem, 90, 1, pp. 5216-5223, (1986)