Research progress in catalytic reforming of low rank coal pyrolysis volatiles

被引：0
|
作者：
Yao N. [1 ]
Cao J. [1 ]
Pang X. [1 ]
Zhao X. [1 ]
Cai S. [1 ]
Xu M. [1 ]
Zhao J. [1 ]
Feng X. [1 ]
Yi F. [1 ]
机构：
[1] Jiangsu Province Engineering Research Center of Fine Utilization of Carbon Resources, China University of Mining & Technology, Jiangsu, Xuzhou
来源：
Huagong Jinzhan/Chemical Industry and Engineering Progress | 2024年 / 43卷 / 05期
关键词：
low rank coal; reaction condition; reactor; thermocatalytic reforming; volatile;
D O I：
10.16085/j.issn.1000-6613.2024-0013
中图分类号：
学科分类号：
摘要：
The clean and efficient utilization of low rank coal is one of the important strategic needs of China. Among coal thermal conversion technologies, catalytic reforming of coal pyrolysis volatile has high efficiency and wide application prospect. Changing process conditions is an important way to increase pyrolysis conversion and product yield. Optimizing reactor design and developing catalysts with high activity and stability are the important development directions of this technology. This paper firstly introduced the catalytic reforming method of low rank coal and its volatiles, on the basis of which the influence of process parameters such as temperature, atmosphere, and residence time, as well as the strategies and challenges for the application of fixed-bed and fluidized-bed reactors, were reviewed. Then, the modification methods of metal catalysts, carbon-based catalysts and zeolite catalysts and the action principles of their post-treatment and in-situ control were analyzed. The catalytic cracking mechanism of pyrolytic volatiles was summarized. The paper also pointed out the bottlenecks of the catalytic reforming of coal pyrolysis volatiles in industrialized production. The key role of the catalytic conversion path of volatile low carbon hydrocarbons and macromolecular compounds in the directional regulation of secondary reactions during coal pyrolysis was identified, and the influence of acid-catalyzed protonation on the deactivation mechanism of catalysts was deeply explored. © 2024 Chemical Industry Press Co., Ltd.. All rights reserved.
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页码：2279 / 2293
页数：14
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共 116 条
  • [1] XIE Kechang, Green transformation of“Wujin”industry, China Coal Industry, 2, pp. 6-7, (2016)
  • [2] China mineral resources, (2023)
  • [3] YUAN Liang, Challenges and countermeasures for high quality development of China's coal industry, China Coal, 46, 1, pp. 6-12, (2020)
  • [4] DING Xiaoxiao, LI Hongjuan, WANG Yatao, Present situation analysis and prospect of classification and utilization of lignite pyrolysis at low temperature, Clean Coal Technology, 25, 5, pp. 1-7, (2019)
  • [5] LEI Zhang, HAO Shu, YANG Jia, Et al., Study on solid waste pyrolysis coke catalyst for catalytic cracking of coal tar, International Journal of Hydrogen Energy, 45, 38, pp. 19280-19290, (2020)
  • [6] HE Mingyuan, ZHANG Kun, GUAN Yejun, Et al., Green carbon science: Fundamental aspects, National Science Review, 10, 9, (2023)
  • [7] HAN Zhennan, JIA Xin, SONG Xingfei, Et al., Engineering thermochemistry to cope with challenges in carbon neutrality, Journal of Cleaner Production, 416, (2023)
  • [8] HU Haoquan, DI Minna, WANG Mingyi, Et al., Upgrading of coal pyrolysis tar by catalytic cracking coupled with steam reforming of ethane, Journal of China Coal Society, 45, 1, pp. 386-392, (2020)
  • [9] HU Haoquan, Coal direct conversion to high quality liquid fuels and chemicals, Chemical Industry and Engineering Progress, 35, 12, pp. 4096-4098, (2016)
  • [10] WU Zhiqiang, YANG Wangcai, TIAN Xueyu, Et al., Synergistic effects from co-pyrolysis of low-rank coal and model components of microalgae biomass, Energy Conversion and Management, 135, pp. 212-225, (2017)
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