Enhanced mechanical, thermal, water and UV aging resistance properties of bamboo fiber/HDPE composites through silane coupling agent modified nano-SiO2-TiO2

Nano-TiO2 is widely employed to enhance the properties of plant fiber reinforced thermoplastic polymer composites due to its chemical inertness, anti-aging, and anti-bacterial properties. However, the enhancement of bamboo fiber/high-density polyethylene (BF/HDPE) composites is limited by the high photocatalytic activity of nano-TiO2 and its poor compatibility with the BF/HDPE matrix. This study employs an organic-inorganic co-modification to prepare BF/HDPE composites reinforced with silane coupling agent KH550 modified nano-SiO2 coated nano-TiO2 (KH550/SiO2-TiO2) by spray coating and melt mixing methods, and the properties of the composites were tested and characterized. The effects of KH550 and KH550/SiO2-TiO2 content on the properties of modified BF/HDPE composites, including mechanical properties, water absorption, thickness swelling rate, water contact angle, thermal stability, and UV aging resistance, which were characterized using methods of mechanical tests, FTIR, UV-Vis, XPS and SEM, both before and after modification. The results indicate that KH550 effectively improves the agglomeration phenomenon and enhances the dispersibility of nano-SiO2-TiO2 in the BF/HDPE composites. The optimal thermal stability is achieved when the BF/HDPE composites modified with a 5 wt% KH550/SiO2-TiO2, while BF/HDPE composites modified with a 3 wt% KH550/SiO2-TiO2 exhibit the better mechanical properties, water resistance, and UV aging resistance compared to other contents. Flexural strength and modulus of KH550/SiO2-TiO2 modified BF/HDPE composites increased by 18.71 % and 17.92 %, tensile strength and modulus increased by 7.74 % and 21.92 %, respectively. The 480-hour water absorption and thickness swelling rate decreased by 18.68 % and 20.73 %, respectively, and the contact angle increased by 19.17 degrees; better thermal stability and color stability was observed. The spray coating method was more effective in improving the properties of the modified BF/HDPE composites than the melt mixing method. Comprehensive analysis indicates that the mechanical properties, water resistance, thermal stability, and UV aging resistance of the BF/HDPE composites reinforced with 3 wt% KH550/SiO2-TiO2 prepared by the spray coating method are significantly enhanced.