Biomimetic synthesis of highly oriented 3D-hexagonal mesoporous silica thin films by evaporation-induced self-assembly process

被引:0
|
作者
Tian, Tian [1 ]
Luo, Zhi-Gang [1 ]
Zhang, Xue-Ao [2 ]
Wu, Wen-Jian [2 ]
Wang, Jian-Fang [2 ]
机构
[1] College of Computer Science, National University of Defense Technology, Changsha 410073, China
[2] College of Aerospace and Material Engineering, National University of Defense Technology, Changsha 410073, China
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关键词
Self assembly - Synthesis (chemical) - Thin films - Three dimensional - Transmission electron microscopy - X ray diffraction analysis;
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摘要
Imitating the mechanism of biomineralization, highly oriented 3D-hexagonal (P63/mmc) mesoporous silica thin films were prepared by evaporation-induced self-assembly (EISA) process using cetyltrimethyl ammonium bromide (CTAB) as the structure-directing agents and tetraethyl orthosilicate (TEOS) as the silica source. The films were deposited on glass substrates by dip-coating method. Their structure were characterized by small-angle X-ray diffraction (XRD), transmission electron microscopy (TEM) and nitrogen adsorption. A possible pathway has been proposed for the formation of 3D-hexagonal mesoporous silica thin films.
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页码:1653 / 1656
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