Preparation and characterization of cellulose nanocrystals from wheat straw and corn stalk

被引:0
作者
Liu Z. [1 ]
He M. [1 ,2 ]
Ma G. [1 ]
Yang G. [2 ]
Chen J. [1 ]
机构
[1] State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology (Shandong Academy of Sciences), Jinan
[2] State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, Guangdong
来源
Palpu Chongi Gisul/Journal of Korea Technical Association of the Pulp and Paper Industry | 2019年 / 51卷 / 02期
关键词
Cellulose nanocrystal; Characterization; Cornstalk; Hydrolysis; Wheat straw;
D O I
10.7584/JKTAPPI.2019.04.51.2.40
中图分类号
学科分类号
摘要
Wheat straw and corn stalk are agricultural residues which are abundant, inexpensive, and readily available source of renewable lignocellulosic biomass. The aim of this study was to prepare cellulose nanocrystals (CNCs) from wheat straw and corn stalk, and to compare their characteristics. To achieve these goals, the CNCs obtained from hydrolysis were characterized in terms of physical, structural and morphological properties. Particle size distribution and atomic force microscopy (AFM) images showed that the CNC from corn stalk (CNC-CS) was more uniform than that from wheat straw (CNC-WS); FTIR spectra implied that acid hydrolysis treatment had no effect on the chemical structure of CNCs. Moreover, the crystallinity of CNC-CS was higher than that of CNC-WS and thermal stability of CNC-WS was observed to be similar to CNC-CS. © 2019 Korean Technical Assoc. of the Pulp and Paper Industry. All rights reserved.
引用
收藏
页码:40 / 48
页数:8
相关论文
共 34 条
[1]  
Lee K.Y., Blaker J.J., Heng J.Y.Y., Murakami R., Bismarck A., PH-trig-gered phase inversion and separation of hy-drophobised bacterial cellulose stabilised pick-ering emulsions, Reactive and Functional Polymers, 85, pp. 208-213, (2014)
[2]  
Sakurada I., Nukushina Y., Ito T., Experimental determination of the elastic modulus of crystalline regions in oriented polymers, Journal of Polymer Science Part A - Polymer Chemistry, 57, 165, pp. 651-660, (1962)
[3]  
Sun B., Zhang M., Hou Q., Liu R., Wu T., Si C., Further characterization of cellulose nanocrystal (CNC) preparation from sulfuric acid hydrolysis of cotton fibers, Cellulose, 23, 1, pp. 439-450, (2016)
[4]  
He M., Lee Y.K., Won J.M., Effect of the modification of PCC with NCC on the paper properties, Journal of Korea TAPPI, 47, 4, pp. 136-143, (2015)
[5]  
Li B.F., Mascheroni E., Piergiovanni L., The potential of nanocellulose in the packaging field: A review, Packaging Technology and Science, 28, pp. 475-508, (2015)
[6]  
Tang X.Z., Kumar P., Alavi S., Sandeep K.P., Recent advances in biopolymers and biopolymer-based nanocomposites for food packaging materials, Critical Reviews in Food Science and Nutrition, 52, pp. 426-442, (2012)
[7]  
John M.J., Thomas S., Biofibers and biocomposites, Carbohydrate Polymers, 71, pp. 343-364, (2008)
[8]  
Huang S., Wu Q., Zhou D., Huang R., Thermal decomposition properties of materials from different parts of corn stalk, BioRe-sources, 10, pp. 2020-2031, (2015)
[9]  
Ruiz H.A., Cerqueira M.A., Silva H.D., Rodriguez-Jasso R.S., Vicente A.A., Teixeira J.A., Biorefinery valorization of au-tohydrolysis wheat straw hemicellulose to be applied in a polymer-blend film, Carbohydrate Polymers, 92, pp. 2154-2162, (2013)
[10]  
Alemdar A., Sain M., Isolation and characterization of nanofibers from agricultural residues: Wheat straw and soy hulls, Biore-source Technology, 99, 6, pp. 1664-1671, (2008)