未找到相关数据
Myoglobin as mimetic enzyme and its analytical application in determination of H2O2
被引：0
作者：
Zheng, Qi
Cao, Qihua
Liu, Zhihong
Cai, Ruxiu
机构：
[1] College of Chemistry and Environmental Engineering, Jianghan University, Wuhan 430052, China
[2] College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1007/BF02836688
中图分类号：
学科分类号：
摘要：
The characteristic of Myoglobin as mimetic enzyme was studied and applied in the determination of H2O2 with o-phenylenediamine as substrate. The absorbance obtained at 40°C was found to be proportional to the concentration of H2O2 in the range of 2.0 × 10-5-2.0 × 10-7 mol/L, with a correlation coefficient of 0.9991. The proposed method is simple and highly sensitive to a detection limit of 2.7 × 108 mol/L. The relative standard deviations were within 5% for the determination of different concentrations of H2O2. Satisfied results were obtained in the determination of H2O2 in rainwater by this method, and the recoveries were at the range of 97.2%-105.4%.
引用
收藏
页码：677 / 681
相关论文