Dopant-induced interactions in spiro-OMeTAD: Advancing hole transport for perovskite solar cells

被引：5

作者：

Dong, Yueyao ^{[1
]}

Rombach, Florine M. ^{[2
]}

Min, Ganghong ^{[1
]}

Snaith, Henry J. ^{[2
]}

Lin, Chieh-Ting ^{[3
,4
]}

Haque, Saif A. ^{[5
]}

Macdonald, Thomas J. ^{[1
]}

机构：

[1] UCL, Dept Elect & Elect Engn, Roberts Bldg, London WC1E 7JE, England

[2] Univ Oxford, Dept Phys, Clarendon Lab, Parks Rd, Oxford OX1 3PU, England

[3] Natl Chung Hsing Univ, Dept Chem Engn, 145 Xingda Rd, Taichung 40227, Taiwan

[4] Natl Chung Hsing Univ, Innovat & Dev Ctr Sustainable Agr, 145 Xingda Rd, Taichung 40227, Taiwan

[5] Imperial Coll London, Dept Chem, Mol Sci Res Hub, London W12 0BZ, England

来源：

MATERIALS SCIENCE & ENGINEERING R-REPORTS | 2025年 / 162卷

基金：

英国工程与自然科学研究理事会;

关键词：

Spiro-OMeTAD; Perovskite solar cells; Perovskite; Photovoltaics; HIGH-PERFORMANCE PEROVSKITE; TIN HALIDE PEROVSKITES; ENERGY-LEVEL SHIFTS; P-TYPE DOPANT; HIGHLY EFFICIENT; ORGANIC SEMICONDUCTORS; LITHIUM-SALTS; STABILITY; LEAD; FILMS;

D O I：

10.1016/j.mser.2024.100875

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Organic semiconductors play a crucial role in the architecture of thin-film electronic devices, particularly as hole transport layers in solar cells. These materials are essential for overcoming significant barriers to improving device lifetime and performance. Among these materials, the small molecule 2,2 ',7,7 '-tetrakis[N,N-di(4methoxyphenyl)amino]-9,9 '-spirobifluorene, known as spiro-OMeTAD, has been instrumental in the development of high-efficiency perovskite solar cells (PSCs) for over a decade. During this time, the additives used to tune the properties of spiro-OMeTAD have undergone significant evolution. Based on current literature, this review examines how interactions in the doping of spiro-OMeTAD have influenced the performance of PSCs, discusses alternatives for future development by highlighting their advantages and limitations, and provides insights into whether spiro-OMeTAD remains the best hole transport material for n-i-p structured PSCs.

引用

页数：22

共 149 条

[51] High efficiency solid-state photovoltaic device due to inhibition of interface charge recombination [J].

2001, American Institute of Physics Inc. (79)

[52] Molecular modification of spiro[fluorene-9,9′-xanthene]-based dopant-free hole transporting materials for perovskite solar cells [J].

Kumar, Vinay ;

Kumar, Deepak ;

Chavan, Rohit D. ;

Kumar, Kodali Phani ;

Yadagiri, Bommaramoni ;

Ans, Muhammad ;

Kruszynska, Joanna ;

Mahapatra, Apurba ;

Nawrocki, Jan ;

Nikiforow, Kostiantyn ;

Mrkyvkova, Nada ;

Siffalovic, Peter ;

Yadav, Pankaj ;

Akin, Seckin ;

Singh, Surya Prakash ;

Prochowicz, Daniel .

JOURNAL OF MATERIALS CHEMISTRY A, 2024, 12 (14) :8370-8380

[53] A Multifunctional Liquid Crystal as Hole Transport Layer Additive Enhances Efficiency and Stability of Perovskite Solar Cells [J].

Lai, Qian ;

Zhuang, Rongshan ;

Zhang, Kun ;

Wu, Tai ;

Xie, Lin ;

Zhao, Rongjun ;

Yang, Lei ;

Wang, Yang ;

Hua, Yong .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 62 (31)

[54] Evidence of Spiro-OMeTAD De-doping by tert-Butylpyridine Additive in Hole-Transporting Layers for Perovskite Solar Cells [J].

Lamberti, Francesco ;

Gatti, Teresa ;

Cescon, Enrico ;

Sorrentino, Roberto ;

Rizzo, Antonio ;

Menna, Enzo ;

Meneghesso, Gaudenzio ;

Meneghetti, Moreno ;

Petrozza, Annamaria ;

Franco, Lorenzo .

CHEM, 2019, 5 (07) :1806-1817

[55] Cascade Reaction in Organic Hole Transport Layer Enables Efficient Perovskite Solar Cells [J].

Lan, Zhineng ;

Huang, Hao ;

Du, Shuxian ;

Lu, Yi ;

Sun, Changxu ;

Yang, Yingying ;

Zhang, Qiang ;

Suo, Yi ;

Qu, Shujie ;

Wang, Min ;

Wang, Xinxin ;

Yan, Luyao ;

Cui, Peng ;

Zhao, Zhiguo ;

Li, Meicheng .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2024, 63 (21)

[56] Stability of Lead and Tin Halide Perovskites: The Link between Defects and Degradation [J].

Lanzetta, Luis ;

Aristidou, Nicholas ;

Haque, Saif A. .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2020, 11 (02) :574-585

[57] Enhancing Intermolecular Interaction of Spiro-OMeTAD for Stable Perovskite Solar Cells with Efficiencies over 24% [J].

Lee, Jung Hwan ;

Ghanem, Tatiana ;

Sanchez, Dario Javier Puchan ;

Josse, Pierre ;

Blanchard, Philippe ;

Ahn, Hyungju ;

Lungerich, Dominik ;

Park, Nam-Gyu ;

Cabanetos, Clement ;

Park, Jong Hyeok .

ACS ENERGY LETTERS, 2023, 8 (09) :3895-3901

[58] Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites [J].

Lee, Michael M. ;

Teuscher, Joel ;

Miyasaka, Tsutomu ;

Murakami, Takurou N. ;

Snaith, Henry J. .

SCIENCE, 2012, 338 (6107) :643-647

[59] Hydrophobic Organic Hole Transporters for Improved Moisture Resistance in Metal Halide Perovskite Solar Cells [J].

Leijtens, Tomas ;

Giovenzana, Tommaso ;

Habisreutinger, Severin N. ;

Tinkham, Jonathan S. ;

Noel, Nakita K. ;

Kamino, Brett A. ;

Sadoughi, Golnaz ;

Sellinger, Alan ;

Snaith, Henry J. .

ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (09) :5981-5989

[60] Insights into the hole transport properties of LiTFSI-doped spiro-OMeTAD films through impedance spectroscopy [J].

Li, Bixin ;

Zhang, Shiyang ;

Xia, Fei ;

Huang, Yongliang ;

Ran, Xueqin ;

Xia, Yingdong ;

Chen, Yonghua ;

Huang, Wei .

JOURNAL OF APPLIED PHYSICS, 2020, 128 (08)

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