Doppler-free two-photon excitation spectroscopy and the Zeeman effect in the channel three region of C6H6

被引：0

作者：

Dae, Youl Baek ^{[1
]}

Chen, JinHai ^{[1
]}

Wang, Jinguo ^{[1
]}

Doi, Atsushi ^{[1
]}

Kasahara, Shunji ^{[1
]}

Baba, Masaaki ^{[2
]}

Kato, Hajime ^{[1
]}

机构：

[1] Molecular Photoscience Research Center, Kobe University, Nada-ku, Kobe 657-8501

[2] Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502

来源：

Bulletin of the Chemical Society of Japan | 2006年 / 79卷 / 01期

关键词：

Doppler-free two-photon excitation spectra and the Zeeman effects for the 1021401 and 10 11401 bands; whose vibrational excess energies are 3412 and 2492 cm-1; respectively; of the S1 1B2u ← S0 1A1g transition in gaseous benzene-h6 have been measured. Rotationally resolved lines up to a rotational excess energy of 945 cm-1 in the 1011401 band; whose excess energy is isoenergetic with the one of the 102140 1 band at low J; have been observed. The density of perturbation is observed to increase around the K = 0 and K = J levels in the 10 11401 band as the rotational energy increases; but line broadening is not observed. It was reported that only the K = 0 lines at low J and the K = J lines at high J were observed as a sharp line and the rest was washed out by broadening in the 10214 01 band. The assignments are confirmed by the Zeeman spectra. The character and magnitude of Zeeman splittings in both bands could be understood as originating from the electronic orbital angular momentum arising from a mixing of the S1 1B2u and S2 1B1u states via J-L coupling. The levels of the S 1 1B2u state are found not to be mixed with a triplet state by the Zeeman effect. © 2006 The Chemical Society of Japan;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Journal article (JA)

引用

页码：75 / 79

共 50 条

[1] Doppler-free two-photon excitation spectroscopy and the Zeeman effect in the "channel three" region of C6H6
Baek, DY
Chen, JH
Wang, JG
Doi, A
Kasahara, S
Baba, M
Katô, H
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2006, 79 (01) : 75 - 79
[2] The Doppler-free two-photon absorption spectroscopy of naphthalene with Zeeman effects
Okubo, M
Misono, M
Wang, JG
Baba, M
Kato, H
JOURNAL OF CHEMICAL PHYSICS, 2002, 116 (21): : 9293 - 9299
[3] Two-photon Doppler-free spectroscopy of trapped atoms
Cesar, CL
Kleppner, D
PHYSICAL REVIEW A, 1999, 59 (06): : 4564 - 4570
[4] The first decades of Doppler-free two-photon spectroscopy
Biraben, Francois
COMPTES RENDUS PHYSIQUE, 2019, 20 (7-8) : 671 - 681
[5] Doppler-free two-photon excitation spectroscopy and the Zeeman effects.: Perturbations in the 1401 and 1011401 bands of the S1 ← S0 transition of C6D6
Baek, DY
Wang, JG
Doi, A
Kasahara, S
Katô, H
Baba, M
JOURNAL OF PHYSICAL CHEMISTRY A, 2005, 109 (32): : 7127 - 7133
[6] Doppler-free two-photon spectrum of SF6 for metrological purposes
Herlemont, F
Khelkhal, M
Legrand, J
Pierre, G
OPTICS LETTERS, 1998, 23 (12) : 957 - 959
[7] Selection of slow molecules in Doppler-free two-photon spectroscopy
Durand, PE
Nogues, G
Bernard, V
Amy, A
Chardonnet, C
ANNALES DE PHYSIQUE, 1995, 20 (5-6) : 601 - 602
[8] Doppler-free two-photon spectroscopy of benzene in a cold supersonic beam
Clara, M
Siglow, K
Neusser, HJ
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2000, 214 (04): : 493 - 501
[9] Two-photon Doppler-free ultraviolet laser spectroscopy on sulphur atoms
Lai, K-F
Salumbides, E. J.
Ubachs, W.
JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2020, 53 (17)
[10] Slow-molecule detection in Doppler-free two-photon spectroscopy
Durand, PE
Nogues, G
Bernard, V
AmyKlein, A
Chardonnet, C
EUROPHYSICS LETTERS, 1997, 37 (02): : 103 - 108

← 1 2 3 4 5 →