The adsorption of Sb(III) in aqueous by KMnO4-modified activated carbon

被引:3
作者
Wang, Xiao-Hui [1 ]
Yu, Ting-Chao [1 ]
Li, Cong [1 ]
Ye, Miao-Miao [1 ]
机构
[1] Department of Civil Engineering, Zhejiang University
来源
Zhejiang Daxue Xuebao (Gongxue Ban)/Journal of Zhejiang University (Engineering Science) | 2012年 / 46卷 / 11期
关键词
Adsorption; KMnO[!sub]4[!/sub]-modified activated carbon; Sb(III);
D O I
10.3785/j.issn.1008-973X.2012.11.014
中图分类号
学科分类号
摘要
In order to improve the adsorption efficiency, granular activated carbon was modified with different concentration of KMnO4 solution under reflux condensation. The characteristics of the four activated carbons was analyzed by scanning electron microscopy (SEM), laser particle size analyzer and specific surface area tests (BET), surface functional groups are examed by Fourier transform infrared spectrometer (FTIR). The static adsorption study involved effect of pH, adsorbate concentration, adsorbent dosage, contact time and temperature. The results indicate that under the initial Sb(III) concentration of 1.5 mg/L, adsorbents dosage of 1.5 g/L, temperature of 298 K, and pH value of 3.00, 0.01 mol/L KMnO4, 0.05 mol/L KMnO4 and the 0.1 mol/L KMnO4, the removal of antimony by activated carbon modified is respectively 87.38%, 97.85% and 99.04%. The experimental data obtained are in good assistant-with the Freundlich adsorption isotherm. In addition, it is found that the pH values have great impacts on the adsorption efficiency.
引用
收藏
页码:2028 / 2034+2067
相关论文
共 15 条
  • [1] He M.-C., Wan H.-Y., Distribution, Speciation, toxicity and bioavailability of antimony in the environment, Progress in Chemistry, 16, 1, pp. 131-135, (2004)
  • [2] Zhang D.-Y., Pan X.-L., Mu G.-J., Et al., Removal of antimony by from water by adsorption to red mud, Technology of Water Treatment, 34, 10, pp. 34-37, (2008)
  • [3] Nasir K., Shujaat A., Et al., Potential of rice husks for antimony removal, Applied Radiation and Isotopes, 52, pp. 31-38, (2000)
  • [4] Polovina M., Babic B., Kaluderovic B., Et al., Surface characterization of oxidized activated carbon cloth, Carbon, 34, pp. 1046-1051, (1998)
  • [5] Li C., Gao N.-Y., Huang T.-L., The research development of the chemical modificaiton of the activated carbon, Water Purification Technology, 24, 4, pp. 50-52, (2005)
  • [6] Bai S.-L., Zhao G.-Y., Fu X.-X., Improvement of adsorption of Cr(III) from aqueous solution by activated carbon, Chemical Research Application, 13, 6, pp. 670-672, (2001)
  • [7] Ding C.-S., Zhu Q.-F., Lu F.-M., Et al., Preparation and characterization of activated carbon modified by KMnO<sub>4</sub> and its Pb<sup>2+</sup> adsorption capability, Urban Environment and Urban Ecology, 24, 1, pp. 42-46, (2011)
  • [8] El-Hendawy A.A., Influence of HNO<sub>3</sub> oxidation on the structure and adsorptive properties of corncob-based activated carbon, Carbon, 41, pp. 713-722, (2003)
  • [9] Molina-Sabio M., Munecas-Vidal M.A., Rodriguez-Reinoso F., Characterization of Porous Solids, 2, (1991)
  • [10] Daifullah A.A.M., Yakout S.M., Elreefy S.A., Adsorption of fluoride in aqueous solutions using KMnO<sub>4</sub>-modified activated carbon derived from steam pyrolysis of rice straw, Journal of Hazardous Materials, 147, pp. 633-643, (2007)