Crystal structure and magnetic properties of the carbon-based ferromagnet prepared by pyrolytic method under high magnetic field

被引:0
作者
Tokue T. [1 ]
Kamishima K. [1 ]
Miyata D. [1 ]
Sato Y. [1 ]
Kakizaki K. [1 ]
Hiratuka N. [1 ]
Imanaka Y. [2 ]
Takamasu T. [2 ]
机构
[1] Graduate School of Science and Engineering, Saitama University, Sakura-ku, Saitama 338-8570
[2] Tsukuba Magnet Laboratory, National Institute for Materials Science, Tsukuba 305-0003
来源
Funtai Oyobi Fummatsu Yakin/Journal of the Japan Society of Powder and Powder Metallurgy | 2011年 / 58卷 / 03期
关键词
Diamond structure; Ferromagnetism; Magnetic field;
D O I
10.2497/jjspm.58.176
中图分类号
学科分类号
摘要
We have prepared the carbon-based ferromagnets by pyrolytic method under high magnetic field and investigated their crystal structure and magnetic properties. The crystal structure was measured by the synchrotron X-ray diffraction experiment. The diffraction peak of a diamond was observed for the ferromagnetic samples. Thus, the carbon-based ferromagnet can be attributed to the ferromagnetic ordering of radical spins generated by defects in the diamond structure. And, the diffraction peak of a diamond of the ferromagnetic samples increased with the applied magnetic field in sample preparation. Therefore, the magnetic field may help to form a three dimensional ferromagnetic structure in the carbon-based ferromagnet. The highest magnetization was 3.0 emu/g at 300 K for the sample prepared under magnetic field at 6 T.
引用
收藏
页码:176 / 180
页数:4
相关论文
共 9 条
  • [1] Iwamura T., Yuukiziseitai kiso, CMC, (1999)
  • [2] Esquinazi P., Spemann D., Hohne R., Setzer A., Hn K.-H., Butz T., Induced magnetic ordering by proton irradiation in graphite, Phys. Rev. Lett., 91, (2003)
  • [3] Coey J.M.D., Venkatesan M., Fitzgerald C.B., Douvalis A.P., Sanders I.S., Ferromagnetism of a graphite nodule from the Canyon Diablo meteorite, Nature, 420, 6912, pp. 156-159, (2002)
  • [4] Ovchinnikov A.A., Spektor V.N., Organic ferromagnets. New results, Synth. Met., 27, (1988)
  • [5] Kamishima K., Miyata D., Sato Y., Tokue T., Kakizaki K., Hiratsuka N., Imanaka Y., Takamasu T., Preparation of pyrolytic magnetic carbon under magnetic field, J. Phys., Conf. Ser., 200, (2010)
  • [6] Murata K., Ueda H., Kawaguchi K., Preparation of carbon powders by pyrolysis of cyclododecane under vacuum and their magnetic properties, Synth. Met., 44, pp. 357-362, (1991)
  • [7] Murata K., Ushijima H., Ueda H., Kawaguchi K., Magnetic properties of amorphous-like carbons prepared from tetraaza compounds by the chemical vapor deposition (CVD) method, H. Chem. Soc., Chem. Commun., pp. 1265-1266, (1991)
  • [8] Murata K., Ushijima H., Ueda H., Kawaguchi K., A stable carbon-based organic magnet, H. Chem. Soc., Chem. Commun., pp. 567-569, (1992)
  • [9] Noda T., Kamishima K., Kakizaki K., Hiratsuka N., Effect of annealing under magnetic field on pyrolytic carbon ferromagnets, J. Magn. Soc. Jpn., 28, pp. 335-338, (2004)