Coupling reactions initiated by oxidative addition to Au(I) complexes

被引：0

作者：

Ito M.

机构：

来源：

Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry | 2021年 / 79卷 / 02期

关键词：

Catalytic oxidation;

D O I：

10.5059/yukigoseikyokaishi.79.155

中图分类号：

学科分类号：

摘要：

Gold-catalyzed reaction initiated by 7r-activation of unsaturated bonds is well-established, where the oxidation state of the gold complex is unchanged throughout the catalytic cycle. Recently, the coupling reactions involving Au(I)/Au(III) catalytic cycle have been developed. The key to success is the kinetic or thermodynamic stabilization of Au(III) species. This mini-review focuses on the generation of Au(III) species by direct oxidative addition of carbon-halogen bond to Au (I) and their application to coupling reactions. © 2021 Society of Synthetic Organic Chemistry. All rights reserved.

引用

页码：155 / 156

页数：1

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