Advances in the enhancement of mechanical and hydrophobic properties of nanocellulose-based packaging materials: A review

As environmental issues are hotly debated worldwide, finding suitable materials to replace petroleum-based materials as the next-generation packaging materials has become a research hotspot. Nanocellulose, as a biomass material widely available in nature, is favored for application in green packaging materials due to its environmentally friendly and bio-friendly characteristics. However, the unstable mechanical properties and strong hydrophilicity of nanocellulose limit its practical application in packaging materials. This paper starts with a discussion of nanocellulose-based packaging materials and focuses on methods to improve their mechanical and hydrophobic properties. The discussion on mechanical properties focuses on the contribution of carbon nanomaterials, which is then combined with hydrophobic modifications (including plant polyphenol modification, esterification, acetylation, in situ polymerization, etc.) to illustrate the impact on the performance of packaging materials in use. The relationship between the hydrophobic characteristics of packaging materials derived from nanocellulose and their comprehensive mechanical properties is meticulously elucidated. Furthermore, a theoretical framework is proposed, positing that enhancing the hydrophobicity of these materials can indirectly augment their mechanical attributes. This insight offers pivotal guidance for the advancement of next-generation, high-performance packaging materials based on nanocellulose.