Visible photoluminescence of praseodymium ions in rare-earth aluminum phosphate glass

被引:0
作者
Han, Xiao-Zhe [1 ]
Fu, Fang-Fang [1 ]
Chen, Bao-Jiu [2 ]
Ma, Tie-Cheng [1 ]
Lin, Hai [1 ]
机构
[1] School of Textile and Material Engineering, Dalian Polytechnic University
[2] Department of Physics, Dalian Maritime University
来源
Faguang Xuebao/Chinese Journal of Luminescence | 2013年 / 34卷 / 10期
关键词
Praseodymium ions; Rare-earth aluminum phosphate glass; Visible photoluminescence;
D O I
10.3788/fgxb20133410.1306
中图分类号
学科分类号
摘要
Visible photoluminescence properties of praseodymium ions in rare-earth aluminum phosphate 5.8Li2O-3CaO-5BaO-16Al2O3 - 4.2La2O3-66P2O5 (LCBALP) glass were investigated and the absolute fluorescence spectra were measured and calibrated in an integrating sphere. The spontaneous emission probability and the maximum stimulated emission cross-section corresponding to the 1D2→3H4 transition are 926.5 s-1 and 3.5×10-21 cm2, respectively. Under the blue LED excitation, the radiant flux and the luminous flux for the visible emission bands of LCBALP glass are identified to be 112.6 μW and 29.7 mlm, respectively. The total quantum yield for the visible fluorescence is determined to be 4.1%. The spectral evaluations of praseodymium ions in optical glass provide a reliable reference in developing optoelectronic devices and compact lighting sources.
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页码:1306 / 1312
页数:6
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共 25 条
  • [11] Zhang J.S., Zhang L.G., Ren J.Y., Et al., Upconversion emission properties in Yb<sup>3+</sup>-Er<sup>3+</sup> co-doped Y<sub>2</sub>O<sub>3</sub>, Y<sub>2</sub>O<sub>2</sub>S and NaYS<sub>2</sub> powder materials, Chin. J. Lumin., 34, 5, pp. 542-546, (2013)
  • [12] Zhao D.X., Liu Y.C., Shen D.Z., Et al., The dependence of emission spectra of rare earth ion on the band-gap energy of Mg<sub>x</sub>Zn<sub>1-x</sub>O alloy, J. Cryst. Growth, 249, 1-2, pp. 163-166, (2003)
  • [13] Wang J., Zhou Y.X., Dai S.X., Et al., State-selective energy transfer from Er<sup>3+</sup> to Eu<sup>3+</sup> in Bi<sub>2</sub>O<sub>3</sub>-GeO<sub>2</sub> - Ga<sub>2</sub>O<sub>3</sub>-Na<sub>2</sub>O glasses, Spectrochim. Acta A, 72, 1, pp. 41-45, (2009)
  • [14] Sun J.M., Zhong G.Z., Fan X.W., Et al., Electroluminescence from ITO/SiO<sub>2</sub>/Ta<sub>2</sub>O<sub>5</sub>/Al multiple-layer structure excited by hot electrons, J. Non-Cryst. Solids, 212, 2-3, pp. 192-197, (1997)
  • [15] Lu W., Hao Z.D., Zhang X., Et al., Ca<sub>3</sub>Al<sub>2</sub>(SiO<sub>4</sub>)<sub>3-δ</sub> Cl<sub>4δ</sub>:Eu<sup>2+</sup>, Mn<sup>2+</sup>: A potential phosphor with energy transfer for near-UV pumped white-LEDs, Opt. Mater., 33, 8, pp. 1262-1265, (2011)
  • [16] Zhang C.Y., Liu X.Y., Qin L., Et al., White microcavity organic light-emitting diode based on one emitting material, J. Lumin., 122-123, pp. 590-592, (2007)
  • [17] Zhang L.L., Peng M.Y., Dong G.P., Et al., An investigation of the optical properties of Tb<sup>3+</sup>-doped phosphate glasses for green fiber laser, Opt. Mater., 34, 7, pp. 1202-1207, (2012)
  • [18] Ming C.G., Song F., Yu Y., Et al., Optical character of Er<sup>3+</sup>/Yb<sup>3+</sup> co-doped P<sub>2</sub>O<sub>5</sub>-CaO-Na<sub>2</sub>O - Al<sub>2</sub>O<sub>3</sub>-AgO phosphate glass, Opt. Commun., 284, 7, pp. 1868-1871, (2011)
  • [19] Guo W., Fu F.F., Yang J., Et al., Radiant and luminous fluxes of Sm<sup>3+</sup> doped heavy metal silicate glass under the excitation of violet light emitting diode, Chin. J. Lumin., 34, 1, pp. 49-53, (2013)
  • [20] Judd B.R., Optical absorption intensities of rare-earth ions, Phys. Rev., 127, pp. 750-761, (1962)