Characterization of sulfonated poly (styrene-divinylbenzene) and poly(divinylbenzene) and its application as catalysts in esterification reaction

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作者
Coutinho, Fernanda M. B. [1 ,2 ]
Rezende, Simone M. [2 ]
Soares, Bluma G. [2 ]
机构
[1] Departamento de Processes Químicos, Institute de Química/UERJ, 20559-900, Rio de Janeiro, RJ, Brazil
[2] Instituto de Macromoléculas Professora Eloisa Mano/UFRJ, 21945-970, Rio de Janeiro, RJ, Brazil
来源
Journal of Applied Polymer Science | 2006年 / 102卷 / 04期
关键词
Polymeric supports based on divinylbenzene (DVB) were prepared by aqueous suspension polymerization in presence or absence of styrene (S), using toluene and n-heptane as diluents of the monomers. Poly(S-DVB) and poly(DVB) were sulfonated with sulfuric acid in presence of 1,2-dichloroethane. The influence of the morphological structure of the supports and as a consequence of the catalyst on the esterification reaction of acetic acid with n-butanol was evaluated. © 2006 Wiley Periodicals, Inc;
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Journal article (JA)
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页码:3616 / 3627
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