Nickel-catalyzed silylation of aryl thianthrenium salts with silylzinc pivalates

被引：0

作者：

Tian, Zhenfeng ^{[1
]}

Cui, Zhili ^{[1
]}

Hu, Ying ^{[1
]}

Zhang, Jiabin ^{[1
]}

Ruan, Liangjie ^{[1
]}

Li, Jie ^{[1
]}

机构：

[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, MOE Key Lab Geriatr Dis & Immunol,Suzhou Key Lab P, Suzhou 215123, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 98期

基金：

中国国家自然科学基金;

关键词：

Catalysis;

D O I：

10.1039/d4cc05395h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A nickel-catalyzed C-S silylation of aryl thianthrenium salts with salt-stabilized silylzinc pivalates is disclosed, thus allowing us to rapidly incorporate silyl motifs into aromatics in a site- and chemoselective fashion. This method is distinguished by its ample scope and facile derivatizations of the aryl silanes for increasing functional molecular complexity. Moreover, modular installation of silyl groups into pharmaceutically active molecules provides a new platform for the synthesis of sila-drugs.

引用

页码：14593 / 14596

页数：4

共 50 条

[41] Nickel-Catalyzed Reductive Carboxylation of Cyclopropyl Motifs with Carbon Dioxide [J].

Moragas, Toni ;

Martin, Ruben .

SYNTHESIS-STUTTGART, 2016, 48 (17) :2816-2822

[42] Nickel-Catalyzed sp 3 C-H Activation [J].

Johnson, Colton E. ;

Li, Shangyu ;

Arora, Ramon ;

Mirabi, Bijan ;

Lautens, Mark .

SYNLETT, 2024, 35 (08) :851-861

[43] An Electrochemically Promoted, Nickel-Catalyzed Mizoroki-Heck Reaction [J].

Walker, Benjamin R. ;

Sevov, Christo S. .

ACS CATALYSIS, 2019, 9 (08) :7197-7203

[44] Nickel-Catalyzed Suzuki-Miyaura Coupling of Aliphatic Amides [J].

Boit, Timothy B. ;

Weires, Nicholas A. ;

Kim, Junyong ;

Garg, Neil K. .

ACS CATALYSIS, 2018, 8 (02) :1003-1008

[45] Synthesis of butyrolactones by nickel-catalyzed reductive cyanation of alkynols in water [J].

Gutiérrez, JLG ;

Jiménez-Cruz, F ;

Espinosa, NR .

TETRAHEDRON LETTERS, 2005, 46 (05) :803-805

[46] Electrocatalytic fluoroalkylation of olefins. Nickel-catalyzed polyfluoroalkylation of allylisocyanurates [J].

Dudkina, Yu. B. ;

Mikhailov, D. Yu. ;

Gryaznova, T. V. ;

Fattakhov, S. G. ;

Budnikova, Yu. G. ;

Sinyashin, O. G. .

RUSSIAN CHEMICAL BULLETIN, 2013, 62 (11) :2362-2366

[47] Nickel-Catalyzed Direct Carboxylation of Olefins with CO2: One-Pot Synthesis of α,β-Unsaturated Carboxylic Acid Salts [J].

Huguet, Nuria ;

Jevtovikj, Ivana ;

Gordillo, Alvaro ;

Lejkowski, Michael L. ;

Lindner, Ronald ;

Bru, Miriam ;

Khalimon, Andrey Y. ;

Rominger, Frank ;

Schunk, Stephan A. ;

Hofmann, Peter ;

Limbach, Michael .

CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (51) :16858-16862

[48] Regio- and Diastereoselective Nickel-Catalyzed Cycloaddition of Activated Cyclopropanes with Allenes [J].

Tombe, Rihoko ;

Iwamoto, Takahiro ;

Kurahashi, Takuya ;

Matsubara, Seijiro .

SYNLETT, 2014, 25 (16) :2281-2284

[49] Nickel-Catalyzed Kumada Cross-Coupling Reactions of Benzylic Sulfonamides [J].

Hewitt, Kirsten A. ;

Herbert, Claire A. ;

Matus, Alissa C. ;

Jarvo, Elizabeth R. .

MOLECULES, 2021, 26 (19)

[50] Recent Trends in Nickel-Catalyzed C-S Bond Formation [J].

Kanchana, U. S. ;

Diana, Elizabeth J. ;

Mathew, Thomas V. .

ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2022, 11 (06)

← 1 2 3 4 5 →