Nickel-catalyzed silylation of aryl thianthrenium salts with silylzinc pivalates

被引：0

作者：

Tian, Zhenfeng ^{[1
]}

Cui, Zhili ^{[1
]}

Hu, Ying ^{[1
]}

Zhang, Jiabin ^{[1
]}

Ruan, Liangjie ^{[1
]}

Li, Jie ^{[1
]}

机构：

[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, MOE Key Lab Geriatr Dis & Immunol,Suzhou Key Lab P, Suzhou 215123, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 98期

基金：

中国国家自然科学基金;

关键词：

Catalysis;

D O I：

10.1039/d4cc05395h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A nickel-catalyzed C-S silylation of aryl thianthrenium salts with salt-stabilized silylzinc pivalates is disclosed, thus allowing us to rapidly incorporate silyl motifs into aromatics in a site- and chemoselective fashion. This method is distinguished by its ample scope and facile derivatizations of the aryl silanes for increasing functional molecular complexity. Moreover, modular installation of silyl groups into pharmaceutically active molecules provides a new platform for the synthesis of sila-drugs.

引用

收藏

页码：14593 / 14596

页数：4

相关论文

共 50 条

[21] Nickel-catalyzed electrophilic amination of organozinc halides [J].

Berman, AM ;

Johnson, JS .

SYNLETT, 2005, (11) :1799-1801

[22] The Critical Role of Reductive Steps in the Nickel-Catalyzed Hydrogenolysis and Hydrolysis of Aryl Ether C-O Bonds [J].

Wang, Meng ;

Zhao, Yuntao ;

Mei, Donghai ;

Bullock, R. Morris ;

Gutierrez, Oliver Y. ;

Camaioni, Donald M. ;

Lercher, Johannes A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (04) :1445-1449

[23] Nickel-catalyzed cross-coupling of aryl or 2-menaphthyl quaternary ammonium triflates with organoaluminum reagents [J].

He, Fang ;

Wang, Zhong-Xia .

TETRAHEDRON, 2017, 73 (30) :4450-4457

[24] Nickel-catalyzed carbonylative cycloaddition of allyl halides and alkenes [J].

del Moral, Daniel ;

Moreto, Josep M. ;

Molins, Elies ;

Ricart, Susagna .

TETRAHEDRON LETTERS, 2008, 49 (49) :6947-6950

[25] Nickel-Catalyzed Esterification of Amides Under Mild Conditions [J].

Jun-Fei Li ;

Yao-Fang Wang ;

Yuan-Yuan Wu ;

Wen-Jing Liu ;

Jun-Wen Wang .

Catalysis Letters, 2020, 150 :874-880

[26] Nickel-Catalyzed Esterification of Amides Under Mild Conditions [J].

Li, Jun-Fei ;

Wang, Yao-Fang ;

Wu, Yuan-Yuan ;

Liu, Wen-Jing ;

Wang, Jun-Wen .

CATALYSIS LETTERS, 2020, 150 (03) :874-880

[27] Nickel-Catalyzed Reductive Allylation of Ketones with Allylic Carbonates [J].

Zhao, Chenglong ;

Tan, Zhuozhen ;

Liang, Zhuye ;

Deng, Wei ;

Gong, Hegui .

SYNTHESIS-STUTTGART, 2014, 46 (14) :1901-1907

[28] Pincer Nickel-Catalyzed Olefination of Alcohols with Benzylphosphine Oxides [J].

Duan, Yu-Tong ;

Yang, Bo ;

Wang, Zhong-Xia .

CHEMISTRY-AN ASIAN JOURNAL, 2024, 19 (11)

[29] Nickel-catalyzed electrochemical carboxylation of epoxides:: mechanistic aspects [J].

Tascedda, P ;

Weidmann, M ;

Dinjus, E ;

Duñach, E .

APPLIED ORGANOMETALLIC CHEMISTRY, 2001, 15 (02) :141-144

[30] Nickel-Catalyzed Reductive Homodimerization of Brominated Polystyrene Chains [J].

Basler, Eleanor D. ;

Chong, Jaden L. ;

Heath, Chloe M. ;

Ching, Katie S. ;

Jennett, Shelby T. ;

Tillman, Eric S. .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2022, 223 (24)

← 1 2 3 4 5 →