Effect of Fly Ash Properties on Strength Development of Microwave-Heated Alkali-Activated Binder

被引:0
|
作者
Zhu H. [1 ,2 ,3 ]
Yu C. [1 ]
Zhang X. [1 ]
Qiao P. [1 ]
Li H. [1 ,2 ,3 ]
机构
[1] College of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an
[2] Ecological Cement Engineering Research Center of Ministry of Education, Xi'an University of Architecture and Technology, Xi'an
[3] Shaanxi Ecological Cement & Concrete Engineering Technology Research Center, Xi'an University of Architecture and Technology, Xi'an
关键词
alkali⁃activated binder; fly ash property; microwave⁃heated; strength development;
D O I
10.3969/j.issn.1007-9629.2023.05.001
中图分类号
学科分类号
摘要
Alkali⁃activated fly ash(AAFA)binders were prepared from fly ash with different calcium content and fineness,and were cured by microwave heating at the early stage of hydration. The developments of compressive strength and microstructure of AAFA specimens were studied and the influence mechanism of microwave heating on strength development was discussed. The results show that increasing the calcium content in fly ash and appropriately reducing the fineness of fly ash can significantly improve the compressive strength of AAFA specimens after microwave heating,but aggravate the strength loss after 28 d. The reason for the strength loss of AAFA specimens cured by microwave heating lies in the dissolution and carbonation of calcium ions in aluminum⁃modified calcium silicate hydrate(C(⁃ A)⁃S⁃H)gel,resulting in the formation of sponge like gel with low density and the decomposition and volume reduction of sodium aluminosilicate hydrate(N⁃A⁃S⁃H)gel. The compressive strength of AAFA specimens prepared from ultrafine fly ash(D50=3.96 μm)is much lower than that of the reference specimen,therefore the former is not suitable for microwave⁃heated curing. © 2023 Tongji University. All rights reserved.
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页码:449 / 456
页数:7
相关论文
共 22 条
  • [1] ZHENG Juanrong, YANG Changli, CHEN Youzhi, Study on mechanism of alkali⁃activated cementitious materials against sulfate attack[J], Journal of Zhengzhou University(Engineering Science), 33, 3, (2012)
  • [2] FU Y, CAI L, WU Y., Freeze⁃thaw cycle test and damage mechanics models of alkali⁃activated slag concrete [J], Construction and Building Materials, 25, 7, (2011)
  • [3] GIOSUE C, MOBILI A, PERNA C D, Et al., Performance of lightweight cement⁃based and alkali⁃activated mortars exposed to high⁃temperature[J], Construction and Building Materials, 220, 30, (2019)
  • [4] DIAZ E I, ALLOUCHE E N, EKLUND S., Factors affecting the suitability of fly ash as source material for geopolymers[J], Fuel, 89, 5, (2010)
  • [5] SHI Huisheng, XIA Ming, GUO Xiaolu, Research progress on reaction mechanism and components of fly ash based polymer, Journal of the Chinese Ceramic Society, 41, 7, (2013)
  • [6] LI Xuechen, LI Hui, BAI Yun, Et al., Effect of micro⁃beads on early mechanical properties of alkali⁃activated fly ash under microwave field, Journal of Building Materials, 23, 4, (2020)
  • [7] ONUTAI S, JIEMSIRILERS S, THAVORNITI P, Et al., Fast microwave syntheses of fly ash based porous geopolymers in the presence of high alkali concentration[J], Ceramics International, 42, pp. 9866-9874, (2016)
  • [8] TEMUUJIN J, VAN RIESSEN A, WILLIAMS R., Influence of calcium compounds on the mechanical properties of fly ash geopolymer pastes[J], Journal of Hazardous Materials, 167, (2009)
  • [9] LIU X H, MA B G, TAN H B, Et al., Preparation of ultrafine fly ash by wet grinding and its utilization for immobilizing chloride ions in cement paste, Waste Management, 113, 15, (2020)
  • [10] LI Yijin, ZHOU Shiqiong, YIN Jian, Et al., Study on mechanical properties of high performance concrete containing ultra⁃fine fly ash [J], Journal of Building Materials, 8, 1, (2005)