Novel polymeric membrane materials for ethanol/water separation via pervaporation

被引:1
作者
Chuntanalerg, P. [1 ]
Naraprawatphong, R. [1 ]
Kulprathipanja, S. [2 ]
Aungkavattana, P. [3 ]
Hemra, K. [3 ]
Chaisuwan, T. [1 ]
Wongkasemjit, S. [1 ]
机构
[1] Petroleum and Petrochemical College, National Center of Excellence for Petrochemicals and Advanced Materials, Chulalongkorn University, Bangkok
[2] UOP, A Honeywell Company, Des Plaines, IL
[3] National Metal and Materials Technology Center (MTEC), Thailand Science Park, Pathumthani
关键词
Ethanol; Pervaporation; Polybenzoxazine membrane; Separation performance; Swelling behavior;
D O I
10.1179/1433075X15Y.0000000007
中图分类号
学科分类号
摘要
In this research, novel polybenzoxazine (PBZ) membranes, synthesized from bisphenol-A, formaldehyde and diamines, were coated on a tubular alumina support by dip-coating technique for ethanol purification application via pervaporation. The effects of dipping time and precursor concentration on the membrane preparation and the separation performance showed that both PBZ membranes were remarkably stable, resistant to swelling, and provided an impressively high separation factor of higher than 10,000 for all ethanol concentration ranges, characteristics implying that they could be a good candidate for high purity ethanol production. © W. S. Maney & Son Ltd 2015.
引用
收藏
页码:398 / 402
页数:4
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