Poly- and perfluorinated compounds in household consumer products

被引:67
作者
Fiedlera S. [1 ]
Pfistera G. [1 ]
Schramm K.-W. [1 ,2 ]
机构
[1] Helmholtz Zentrum München - National Research Centre for Environmental Health, Institute of Ecological Chemistry, Neuherberg 85764
[2] Department für Biowissenschaftliche Grundlagen, Technischen Universität, TUM - Wissenschaftszentrum Weihenstephan für Ernährung und Landnutzung, Freising 85350
基金
美国国家环境保护局;
关键词
Exposure; Fluorotelomer alcohols; Perfluorooctane sulfonate; Perfluorooctanoate;
D O I
10.1080/02772248.2010.491482
中图分类号
学科分类号
摘要
Several household consumer products were analyzed for their content of perfluorooctanoate (PFOA), perfluorooctane sulfonate (PFOS), and fluorotelomer alcohols (FTOH) by nanoflow ultra performance liquid chromatography - mass spectrometry and gas chromatography - mass spectrometry. Among the investigated products, which are applied as sprays, were impregnating agents, cleaning agents, lubricants, and conditioners. In 14 of the 26 products analyzed, at least one polyfluorinated compound (PFC) was detected in 14 samples. 8: 2 FTOH was the dominating PFC with concentrations up to 149 μgmL-1. The maximum concentration of PFOA was 14.5 μgmL-1, whereas PFOS was not detected in any sample. Investigated PFCs were mostly found in impregnating agents and lubricants, but were not detected in cleaning agents and conditioners. In FTOH-containing impregnating agents, similar ratios between 6: 2 FTOH, 8: 2 FTOH, and 10: 2 FTOH were found. FTOH proportions in PFC-containing lubricants were similar as well. Total human exposure to PFC from consumer product aerosols for three different scenarios was estimated to be between 42.8 and 464 ng kg-1 per day. © 2010 Taylor & Francis.
引用
收藏
页码:1801 / 1811
页数:10
相关论文
共 40 条
[1]  
Barber J.L., Berger U., Chaemfa C., Huber S., Jahnke A., Temme C., Jones K.C., Analysis of per- and polyfluorinated alkyl substances in air samples from Northwest Europe, Journal of Environmental Monitoring, 9, pp. 530-541, (2007)
[2]  
Begley T.H., White K., Honigfort P., Twaroski M.L., Neches R., Walker R.A., Perfluorochemicals: Potential sources of and migration from food packaging, Food Additives and Contaminants, 22, pp. 1023-1031, (2005)
[3]  
Biegel L.B., Hurtt M.E., Frame S.R., O'Connor J.C., Cook J.C., Mechanisms of extrahepatic tumor induction by peroxisome proliferators in male CD rats, Toxicological Sciences, 60, pp. 44-55, (2001)
[4]  
Calafat A.M., Kuklenyik Z., Caudill S.P., Reidy J.A., Needham L.L., Perfluorochemicals in pooled serum samples from United States residents in 2001 and 2002, Environmental Science and Technology, 40, pp. 2128-2134, (2006)
[5]  
Dinglasan M.J.A., Ye Y., Edwards E.A., Mabury S.A., Fluorotelomer alcohol biodegradation yields poly- and perfluorinated acids, Environmental Science and Technology, 38, pp. 2857-2864, (2004)
[6]  
Dreyer A., Ebinghaus R., Polyfluorinated compounds in ambient air of the German bight, North Sea, and two land-based sites in the vicinity of Hamburg, Germany, Atmospheric Environment, 43, pp. 1527-1535, (2009)
[7]  
Dreyer A., Weinberg I., Temme C., Ebinhaus R., Polyfluorinated compounds in the atmosphere of the Atlantic and Southern Oceans: Evidence for a global distribution, Environmental Science and Technology, 43, pp. 6507-6514, (2009)
[8]  
Ellis D.A., Martin J.W., de Silva A.O., Mabury S.A., Hurley M.D., Andersen M.P.S., Wallington T.J., Degradation of fluorotelomer alcohols: A likely atmospheric source of perfluorinated carboxylic acids, Environmental Science and Technology, 38, pp. 3316-3321, (2004)
[9]  
Ellis D.A., Martin J.W., Mabury S.A., Hurley M.D., Andersen M.P.S., Wallington T.J., Atmospheric lifetime of fluorotelomer alcohols, Environmental Science and Technology, 37, pp. 3816-3820, (2003)
[10]  
(2002)