The fluctuating standard potential of lithium in organic solvents

被引：0

作者：

Zhang, Bohai ^{[1
]}

Jia, Yunzhe ^{[1
]}

Zhou, Yuhao ^{[1
]}

Ye, Shihai ^{[1
]}

Yan, Tianying ^{[1
]}

Gao, Xue-Ping ^{[1
]}

机构：

[1] Institute of New Energy Material Chemistry, Nankai University, School of Materials Science and Engineering, Tianjin,300350, China

来源：

Chemical Communications | 2022年 / 58卷 / 30期

关键词：

Electrochemical electrodes - Electrolytes - Lithium - Thermodynamic properties;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The standard potential of a lithium metal electrode versus the standard hydrogen electrode was calculated by constructing the thermodynamic cycle in a hypothetical electrochemical cell with a dual-phase electrolyte. It is demonstrated that the standard potential of the lithium metal electrode can fluctuate over 0.5 V in different organic solvents, and is correlated to the modified donor number by the entropy of fusion of the solvents. © 2022 The Royal Society of Chemistry.

引用

页码：4747 / 4750

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