The fluctuating standard potential of lithium in organic solvents

被引：0
|
作者：
Zhang, Bohai [1 ]
Jia, Yunzhe [1 ]
Zhou, Yuhao [1 ]
Ye, Shihai [1 ]
Yan, Tianying [1 ]
Gao, Xue-Ping [1 ]
机构：
[1] Institute of New Energy Material Chemistry, Nankai University, School of Materials Science and Engineering, Tianjin,300350, China
来源：
Chemical Communications | 2022年 / 58卷 / 30期
关键词：
Electrochemical electrodes - Electrolytes - Lithium - Thermodynamic properties;
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摘要：
The standard potential of a lithium metal electrode versus the standard hydrogen electrode was calculated by constructing the thermodynamic cycle in a hypothetical electrochemical cell with a dual-phase electrolyte. It is demonstrated that the standard potential of the lithium metal electrode can fluctuate over 0.5 V in different organic solvents, and is correlated to the modified donor number by the entropy of fusion of the solvents. © 2022 The Royal Society of Chemistry.
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页码：4747 / 4750
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