Synthesis, characterisation and crystal structure of a copper(II) dichromate complex with the N,N′-Bis(2-pyridylmethylene)butane-1,4-diamine schiff base ligand

被引：0

作者：

Department of Chemistry, Jadavpur University, Kolkata-700 032, West Bengal, India ^{[1
]}

不详 ^{[2
]}

机构：

[1] Department of Chemistry, Jadavpur University, Kolkata-700 032, West Bengal

[2] Department of Chemistry, Monash University, Clayton

来源：

Z. Naturforsch. Sect. B J. Chem. Sci. | 2007年 / 4卷 / 495-500期

关键词：

Copper(II); Dichromate; Schiff base; Synthesis; X-ray structure;

D O I：

10.1515/znb-2007-0402

中图分类号：

学科分类号：

摘要：

The new complex Cu[L1]Cr2O7has been synthesised with the N,N′-bis(2-pyridylmethylene) butane-1,4-diamine Schiff base L1, [NC5H4CH=N(CH2) 4N=CHC5H4N], and characterised with elemental analyses and different spectroscopic and electrochemical studies. The structure of the new complex has been established by single crystal X-ray diffraction. The complex crystallises in the monoclinic system with space group P21/c having cell parameters a = 14.7(5), b = 9.22(2), c = 16.2(5) Å, β= 116.9(1)°, and Z = 4. The Cr2O72- unit is bonded through one terminal oxygen donor end to the central Cu(II) chelated by the Schiff base ligand. © 2007 Verlag der Zeitschrift für Naturforschung.

引用

页码：495 / 500

页数：5

共 50 条

[31] N,N′-dipyridoxyl(ethylenediamine) schiff-base ligand and its square-pyramidal copper(II) complex: Synthesis, experimental and theoretical characterization
S. A. Beyramabadi
A. Morsali
S. H. Vahidi
M. J. Khoshkholgh
A. A. Esmaeili
Journal of Structural Chemistry, 2012, 53 : 460 - 467
[32] Synthesis, characterisation and crystal structure of a 1,4-diazacycloheptane complex of copper(II)
Sen, S
Saha, MK
Mitra, S
Edwards, AJ
Clegg, W
POLYHEDRON, 2000, 19 (15) : 1881 - 1885
[33] Synthesis, electrochemistry and in situ spectroelectrochemistry of a new Co(III) thio Schiff-base complex with N,N′-bis(2-aminothiophenol)-1,4-bis(carboxylidene phenoxy)butane
Yilmaz, Ismail
Temel, Hamdi
Alp, Hueseyin
POLYHEDRON, 2008, 27 (01) : 125 - 132
[34] Synthesis, crystal structure and antibacterial activities of mixed ligand copper(II) and cobalt(II) complexes of a NNS Schiff base
Ghosh, Mahendra
Layek, Manas
Fleck, Michel
Saha, Rajat
Bandyopadhyay, Debasis
POLYHEDRON, 2015, 85 : 312 - 319
[35] Synthesis and crystal structure determination of a nickel(II) complex of an acyclic pentadentate (N5) mono Schiff base ligand.
Keypour, H
Salehzadeh, S
Pritchard, RG
Parish, RV
MOLECULES, 2001, 6 (11) : 909 - 914
[36] Synthesis and Crystal Structure of a Novel Copper(II) Complex Derived from N,N′-Bis(3-ethoxysalicylidene)-1,2-ethanediamine
Cui, Yong-Ming
Hou, Peng
You, Zhong-Lu
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2011, 41 (07) : 750 - 753
[37] Synthesis, crystal structure, spectral properties and catalytic activity of a binuclear copper(II) complex containing a Schiff base ligand
Pattanayak, Poulami
Pratihar, Jahar Lal
Patra, Debprasad
Brandao, Paula
Mal, Dasarath
Felix, Vitor
POLYHEDRON, 2013, 59 : 23 - 28
[38] Synthesis, crystal structure and electronic properties of bis(N-2-bromophenyl-salicydenaminato)copper(II) complex
Vafazadeh, Rasoul
Hayeri, Vahid
Willis, Anthony C.
POLYHEDRON, 2010, 29 (07) : 1810 - 1814
[39] Copper(II) complexes with a (N,O)-donor Schiff base ligand : Syntheses, crystal structure, DNA interaction study and molecular docking
Dey, Dhananjay
Pal, Sukanta
Bag, Partha Pratim
Saha, Subhasish
Chandraleka, Saravanan
Dhanasekaran, Dharumadurai
Kole, Niranjan
Biswas, Bhaskar
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2015, 92 (02) : 191 - 202
[40] Synthesis, structure and magnetic property of a copper(II)-cobalt(II) heteronuclear complex with Schiff base ligand
Tan, Yuye
Huang, Junjie
Lu, Hui
Chi, Tao
Sun, Jianhua
INORGANIC AND NANO-METAL CHEMISTRY, 2020, 50 (03) : 110 - 113

← 1 2 3 4 5 →