Structure and performance of Cu/ZrO2 catalyst for the synthesis of methanol from CO2 hydrogenation

被引：2

作者：

Zhuang H.-D. ^{[1
,2
]}

Bai S.-F. ^{[1
,2
]}

Liu X.-M. ^{[1
,2
]}

Yan Z.-F. ^{[1
,2
]}

机构：

[1] State Key Laboratory for Heavy Oil Processing, China University of Petroleum (East China)

[2] Key Laboratory of Catalysis, CNPC, China University of Petroleum (East China)

来源：

Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology | 2010年 / 38卷 / 04期

关键词：

Carbon dioxide hydrogenation; Copper oxide; Impregnation-precipitation; Methanol synthesis; XPS; Zirconia;

D O I：

10.1016/s1872-5813(10)60041-2

中图分类号：

学科分类号：

摘要：

Cu/ZrO2 catalysts were prepared through fractional precipitation, impregnation-precipitation and solid-state reaction methods and characterized by N2 sorption, XRD, TPR, in-situ IR and XPS techniques. Their catalytic performances in methanol synthesis from CO2 hydrogenation were investigated. The results showed that the physical structure and reducibility as well as the interaction between Cu and ZrO2 of a Cu/ZrO2 catalyst are greatly affected by the preparation method. The catalytic performance of Cu/ZrO2 is mainly determined by the interaction between Cu and ZrO2 rather than by the surface area. Compared with the catalysts prepared by other methods, the Cu/ZrO2 catalyst prepared by impregnation-precipitation is provided with higher CuO dispersion and stronger interaction between Cu and ZrO2; it also exhibits higher CO2 conversion and higher methanol yield when used as catalyst in the synthesis of methanol from CO2 hydrogenation.

引用

页码：462 / 467

页数：5

共 20 条

[1] Sun Z.-G., Yang R.-Q., Li W.-Z., Fan W.-Y., Study on low-temperature synthesis of methanol from syngas containing CO2, Industrial Catalysis, 16, 11, pp. 48-51, (2008)
[2] Xu X.-M., Progress in methanol synthesis from carbon dioxide and hydrogen, Chemical Technology Market, 31, 12, pp. 33-34, (2008)
[3] Sloczynski J., Grabowski R., Olszewski P., Kozlowska A., Stoch J., Lachowska M., Skrzypek J., Effect of metal oxide additives on the activity and stability of Cu/ZnO/ZrO2 catalysts in the synthesis of methanol from CO2 and H2, Appl Catal A, 310, pp. 127-137, (2006)
[4] Yin Y.-Q., Xiao T.-C., Su J.-X., Wang H.-T., Lu Y.-L., Feng X.-S., Li S.-B., Study for adsorptive behavior of CO and H2 on Cu-ZnO based catalyst, Natural Gas Chemical Industry, 14, 5, (2000)
[5] Guo H.-G., Han W.-F., Shen J.-L., Liu H.-Z., Studies on deactivation of copper-based methanol synthesis catalysts, Industrial Catalysis, 11, 3, (2003)
[6] Wang Y.-X., Zhang R., Wang X.-S., Yao D.-J., Tang W., Research and development on methanol synthesis catalyst containing manganese, Liaoning Chemical Industry, 33, 3, (2004)
[7] Yu F.-W., Ji J.-B., Zheng Y.-F., Liu H.-Z., Copper-based catalyst for methanol synthesis prepared with dual-frequency ultrasonic technology, Petrochemical Technology, 33, 9, (2004)
[8] Liu X.-M., Xing W., Yan Z.-F., Surface and pore structure modification of mesoporous nano-zirconia zeolites, Chinese Journal of Inorganic Chemistry, 21, 2, pp. 191-192, (2005)
[9] Liu X.-M., Lu G.Q., Yan Z.-F., Nanocrystalline zirconia as catalyst support in methanol synthesis, Appl Catal A, 279, 1-2, pp. 241-245, (2005)
[10] Guo X.-J., Chen B.-Y., Bao G.-L., Li L.-M., Structure and properties of copper-based catalysts for methanol synthesis prepared by different precipitation methods, Natural Gas Chemical Industry, 28, 2, (2003)

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