Synthesis process of castor oil glycidyl ether

被引：0

作者：

Wang, Fang ^{[1
,2
]}

Wang, Chuan-Zhu ^{[2
]}

Kuai, Jun-Tao ^{[1
]}

Li, Da-Qian ^{[2
]}

Zhu, Xin-Bao ^{[1
,2
]}

机构：

[1] College of Chemical Engineering, Nanjing Forestry University, Nanjing

[2] Anhui Engineering Research Center of Epoxy Resin and Additives, Huangshan

来源：

Chemistry and Industry of Forest Products | 2015年 / 35卷 / 04期

关键词：

Castor oil; Epoxy resin; Glycidyl ether;

D O I：

10.3969/j.issn.0253-2417.2015.04.018

中图分类号：

学科分类号：

摘要：

Using castor oil and epoxy chloropropane(ECH) as the main raw materials under the alkali condition, a novel castor oil glycidyl ether (COGE) was synthesized through two steps, namely open loop and closed loop reaction. The effects of process conditions on epoxy values were investigated. The results showed that the highest epoxy value the product achieved was 1.56 mmol/g under the condition that the open loop reaction was set at 0.4% catalyst dosage, 3.5 molar ratio of ECH and castor oil, and reaction temperature at 60℃ for 5 h, and as well as the close-loop reaction was set 0.4% catalyst dosage, 1.1 molar ratio of NaOH and ECH, and reaction temperature at 60℃ for 6 h. The chemical structure of the castor oil glycidyl ether was characterized by FT-IR and 1H NMR. TGA analysis showed that castor oil glycidyl ether had good thermal stability at high temperature. Viscosity test showed that the product could reduce the viscosity of epoxy resin. ©, 2015, The Editorial of «Chemistry and Industry of Forest Products». All right reserved.

引用

页码：112 / 116

页数：4

共 10 条

[1] Karak N., Rana S., Cho J.W., Synthesis and characterization of castor oil-modified hyperbranched polyurethanes, Journal of Applied Polymer Science, 112, 2, pp. 736-743, (2009)
[2] Yeganeh H., Talemi P.H., Preparation and properties of novel biodegradable polyurethane networks based on castor oil and poly(ethylene glycol), Polymer Degradation and Stability, 92, 3, pp. 480-489, (2007)
[3] Wang H.-J., Rong M.-Z., Zhang M.-O., Et al., Biodegradable foam plastics based on castor oil, Biomacromolecules, 9, 2, pp. 615-623, (2008)
[4] De B., Gupta K., Mandal M., Et al., Biodegradable hyperbranched epoxy from castor oil-based hyperbranched polyester polyol, Acs Sustainable Chemistry and Engineering, 2, 3, pp. 445-453, (2014)
[5] He Y.-X., Li G.-M., Liu X., Synthesis and characterization of epoxidized castor oil, Chinese Journal of Applied Chemistry, 27, 1, pp. 27-31, (2010)
[6] Ray D., Ghorui S., Bandyopadhyay N.R., Et al., New materials from maleated castor oil/epoxy resin blend reinforced with fly ash, Industrial and Engineering Chemistry Research, 51, 6, pp. 2603-2608, (2012)
[7] Wang H.-F., Wang J.-F., Zhang W.-H., Et al., The method for preparing epoxidized methyl actoricinoleate, Journal of Jilin Institute of Chemical Technology, 12, 2, pp. 72-74, (1995)
[8] Park S.J., Jin F.-L., Lee J.R., Synthesis and thermal properties of epoxidized vegetable oil, Macromolecular Rapid Communications, 25, 6, pp. 724-727, (2004)
[9] Abbasi E., Vatankhah M., Hosseini Y., Et al., Synthesis, structure, and mechanical properties of castor oil-based polyamidoamines toughened epoxy coatings, Journal of Applied Polymer Science, 128, 6, pp. 4023-4030, (2013)
[10] Zhu L., Jin F.-L., Park S.J., Thermal stability and fracture toughness of epoxy resins modified with epoxidized castor oil and Al<sub>2</sub>O<sub>3</sub> nanoparticles, Bulletin of The Korean Chemical Society, 33, 8, pp. 2513-2516, (2012)

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