Polyurethanes Made with Blends of Polycarbonates with Different Molecular Weights Showing Adequate Mechanical and Adhesion Properties and Fast Self-Healing at Room Temperature

被引:0
作者
Paez-Amieva, Yuliet [1 ]
Mateo-Oliveras, Noemi [1 ]
Martin-Martinez, Jose Miguel [1 ]
机构
[1] Univ Alicante, Adhes & Adhes Lab, Alicante 03080, Spain
关键词
polycarbonate polyol; soft segments; length of the soft segments; intrinsic self-healing at 20 degrees C; blends of polyols; mechanical properties; adhesion; BONDS;
D O I
10.3390/ma17225532
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Dynamic non-covalent interactions between polycarbonate soft segments have been proposed for explaining the intrinsic self-healing of polyurethanes synthesized with polycarbonate polyols (PUs) at 20 degrees C. However, these self-healing PUs showed insufficient mechanical properties, and their adhesion properties have not been explored yet. Different PUs with self-healing at 20 degrees C, acceptable mechanical properties, and high shear strengths (similar to the highest ones reported in the literature) were synthesized by using blends of polycarbonate polyols of molecular weights 1000 and 2000 Da (CD1000 + CD2000). Their structural, thermal, rheological, mechanical, and adhesion (single lap-shear tests) properties were assessed. PUs with higher CD1000 polyol contents exhibited shorter self-healing times and dominant viscous properties due to the higher amount of free carbonate groups, significant carbonate-carbonate interactions, and low micro-phase separation. As the CD2000 polyol content in the PUs increased, slower kinetics and longer self-healing times and higher mechanical and adhesion properties were obtained due to a dominant rheological elastic behavior, soft segments with higher crystallinities, and greater micro-phase separation. All PUs synthesized with CD1000 + CD2000 blends exhibited a mixed phase due to interactions between polycarbonate soft segments of different lengths which favored the self-healing and mobility of the polymer chains, resulting in increased mechanical properties.
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页数:19
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